该文以物理化学的吸附等温式为例说明实验数据线性拟合应注意的问题。结果表明,线性拟合结果的合理性不仅要考虑|R|的大小,同时还要求处理的数据精度相当。对类似于兰格缪尔吸附等温式的双曲型方程,建议采用单倒数法而不是通常使用的双倒数法进行线性化拟合。
In this paper,the adsorption isotherm of physical chemistry is taken as an example to illustrate some problems existed on the linear fit of experimental data.The results show that the rationality of linear fit depends on not only the value of |R|,but also the accuracy of processing data.Upon the hyperbolic equation which is similar to Langmuir adsorption isotherm,the single-reciprocal method instead of the usually double-reciprocal method is proposed.