用乙酰化的没食子酸对魔芋葡甘露聚糖进行酯化改性,并对改性产物性能进行了表征。结果表明,当反应底物魔芋葡甘露聚糖与三乙酰没食子酰氯的质量比为1:3.6时,改性产物的酯化度高达0.6281。与未改性的魔芋葡甘露聚糖相比,改性魔芋葡甘露聚糖的粘度、稳定性、冻融稳定性均发生不同程度的改变。醋酸钠法对改性产物的乙酰保护基具有一定的脱除效果,其得率约71.5%。研究结果可为魔芋葡甘露聚糖的改性和精细化利用提供参考数据。
The modification of konjac glucomannan(KGM) with acetylized gallic acid and the properties of modified products were investigated.The results indicated that when the mass ratio of KGM to triacetyl galloylchloride was 1:3.6,the substitution degree of modified product was up to 0.6281.Modified KGM had viscosity,stability and freeze-thaw stability different from those of KGM.Triacetyls in the modified product could be partly removed by using sodium acetate method and the yield of end product was about 71.5 %.The data can offer reference to the modification and fine application of konjac glucomannan.