中文摘要：

合成了有机锡化合物（C6H5）3SnCl，通过元素分析、红外光谱和核磁共振氢和锡谱对其结构进行了表征。用X-射线单晶衍射测定了该化合物的晶体和分子结构。化合物晶体为三斜晶系，空间群Pi，a=9．740（9）А，b=18．674（17）A，c=19．010（17）A，a=105．513（14）°，β=90．036（14）β，γ=90．258（15）β，V=3332（5）A^3，Z=8，De=1．537Mg／m^3，μ=1．682mm^-1，F（000）=1520，R=0．0458，ωR=0．1030。锡原子呈畸变四面体构型。

英文摘要：

Organotin compound（C6H5）3SnCl was synthesized with its crystal, and molecular structure determined by X-ray single crystal diffraction method. A crystal of the said compound was tficlinic with a space group Pi, a = 9.740（9）A, b = 18.674（17）A,c = 19.010（17）A,a = 105.513（14）°,β =90.036（14）°, γ = 90.258（15）°, V= 3 332（5）A, Z = 8,Dc = 1.537 Mg/m^3, μ = 1.682 mm^-1, F（000）= 1 520, R = 0.045 8, ωR = 0. 103 0. In this compound,the tin atom showed a distorted tetrahedral configuration.