文章以生物质稻秸为研究对象,利用AspenPlus软件建立了串行流化床生物质合成气费托(Fischer-Tropsch,FT)合成的模型,研究了不同反应条件包括气化温度、气化压力、气化过程水蒸气与生物质的比率(m(S)/m(B))、合成气中n(H2)/n(CO)、合成温度以及合成压力对合成工艺的影响。结果表明.采用蛋壳型钻基催化剂,对于制费托合成油为目的的串行流化床生物质气化系统,用于费托合成的适宜工况条件为:建议气化温度850℃左右,气化压力0.1MPa.m(S)/m(B)约为0.4,合成气中n(H2)/n(CO)保持在2.0~2.1之间.合成反应温度取220℃为佳,反应压力选取2.0MPa左右。在此工况下.每kg稻秸可以获得约为0.54mol的费托合成油。
Taking the rice straw as the research object, simulation of Fischer-Tropsch(FT) synthesis from biomass gasification in interconnected fluidized beds was carried out using Aspen Plus software. Effects of operating parameters including gasification temperature and pressure, steam/biomass ratio (m (S)/m (B)), n ( H2 )/n (CO) ratio, synl hesis temperal ure and pressure on the synthesis were ana- lyzed. The results are as follows, the gasification temperature and pressure are suggested to be re- spectively controlled at about 850 ℃ and 0.1 MPa, and the m(S)/m(B) ratio of 0.4 operates better in the interconnected fluidized beds biomass gasification system with the purpose of FT-oil production in the case of eggshell cobalt-based catalysis. Furthermore, the gasification pressure of ambient pressure and the n(H2)/n(CO) ratio of 2.0-2.1 are proposed to be controlled. The synthesis temperature is suggested to be controlled at about 220℃ and the pressure of 2.0 MPa is adopted. On the optimal op crating conditions, the maximum FT oil yield may reach 0. 54 tool per kilogram rice straw.