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一种以三聚氯氰为桥基的新型小分子功能活性染料的合成
  • ISSN号:1005-1511
  • 期刊名称:《合成化学》
  • 时间:0
  • 分类:TQ174.75[化学工程—陶瓷工业;化学工程—硅酸盐工业] TB383[一般工业技术—材料科学与工程]
  • 作者机构:[1]School of Chemistry and Chemical Engineering, Anhui University, Hefei 230601, China, [2]State Key Laboratory for Modification of Chemical Fibers and Polymer Materials & College of Material Science and Engineering, Donghua University, Shanghai 201620, China, [3]College of Chemistry, Chemical Engineering and Biotechnology, Donghua University, Shanghai 201620, China
  • 相关基金:This research was financially supported by the National Natural Science Foundation of China (Nos. 51372004, 21171034 and 21271040), the Shanghai Municipal Natural Science Foundation for Youths (No. 12ZR144100) and "Chen Guang" project (No. 12CG37) supported by Shanghai Municipal Education Commission and Shanghai Education Development Foundation.
中文摘要:

有一致形态学和可控制的尺寸的 Hydroxyapatite (幸运) nanoparticles 被分子的模板成功地综合热水的途径。包括乙醇,乙二醇,甘油和 butanol 的器官的白酒被用作模板调整成核和水晶生长。综合粉末被 X 光检查衍射, Fourier 红外线的光谱和传播电子显微镜学描绘。结果证明获得的幸运粒子是分子的结构有的一致像杆的晶体,和模板幸运粒子的形态学和尺寸上的重要效果。与更长恐水病的组一起的模板分子导致了更长的粒子长度和更大的方面比率。与模板分子的集中相比,分子的结构显示出的模板对控制幸运形态学和尺寸的更大的影响。而且,烷基白酒模板准备的这些像杆的幸运粒子的形成机制被讨论。而且,热水的处理温度和时间能也为幸运 nanoparticles 的控制准备被使用。

英文摘要:

Hydroxyapatite (HAP) nanoparticles with uniform morphologies and controllable size were synthesized successfully by molecular template hydrothermal approach. The organic alcohols including ethanol, glycol, glycerol and butanol were used as templates to regulate the nucleation and crystal growth. The synthesized powders were characterized by X-ray diffraction, Fourier infrared spectrum and trans- mission electron microscopy. The results showed that the obtained HAP particles were uniform rod-like crystals, and the template molecular structures had significant effect on the morphology and size of HAP particles. The template molecules with longer hydrophobic groups resulted in longer particle length and larger aspect ratio. Compared with the concentration of template molecules, the template molecular structure showed larger influence on controlling the HAP morphology and size. Furthermore, the for- mation mechanism of these rod-like HAP particles prepared by alkyl alcohol templates was discussed. Moreover, hydrothermal treatment temperature and time could be also used for controlled preparation of HAP nanoparticles.

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期刊信息
  • 《合成化学》
  • 中国科技核心期刊
  • 主管单位:四川省科学技术协会
  • 主办单位:四川省化学化工学会 中国科学院成都有机化学有限公司
  • 主编:熊成东
  • 地址:成都市武侯区人民南路四段9号
  • 邮编:610041
  • 邮箱:hchx@cioc.ac.cn
  • 电话:028-85255007
  • 国际标准刊号:ISSN:1005-1511
  • 国内统一刊号:ISSN:51-1427/O6
  • 邮发代号:62-196
  • 获奖情况:
  • 1998年上C.A千名表(803位),1999年入选《中国科学引文数据库》来源期刊,1999-2002年作为《中国学术期刊综合评价数据库》...
  • 国内外数据库收录:
  • 美国化学文摘(网络版),中国中国科技核心期刊,中国北大核心期刊(2008版),中国北大核心期刊(2011版),英国英国皇家化学学会文摘
  • 被引量:7579