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中文摘要：
在溶剂热条件下，以原位反应为基础合成了两个碘化物（C6H8N3）^＋I3^-（1，C6H8N3=2，3-dihydroimidazo[1，2-a]pyrimidin-1-ium，2，3-二氢咪唑[1，2-α]-嘧啶鳞阳离子）和[（Cu3I4）（C8H17N2）]（2，C8H17N2=N-ethyl-4-aza-1-azonia—bicyclo[2．2．2]octane，N-乙基三乙烯二铵阳离子）．用元素分析、粉末X射线衍射及单晶X射线衍射等对化合物进行了表征．结果表明，化合物1属于三斜晶系，P1^-空间群，a=0．74281（15）nm，b=0．84241（17）nm，c=0．9993（2）nm，α=82．02（3）°，β=83．30（3）°，γ=82．92（3）°，V=0．6114（2）nm^3。化合物2属于单斜晶系，P21/c空间群，a=0．68924（14）nm，b=1．0786（2）nm，c=2．2779（5）nm，β=94．84（3）°，V=1．6874（6）nm^3．在两个化合物合成中存在两种不同类型的配体原位合成反应，即化合物1的2-氨基嘧啶和乙醇的成环反应与化合物2的三乙烯二胺和乙醇的烷基化反应．
英文摘要：
Two I-containing compounds, （ C6H8N3 ） ^＋ I3^- （1, C6H7 N3 = 2,3-dihydroimidazo [ 1,2-a] pyrimidine-1-ium） and [ （ Cu3I4 ） （ C8H17N2 ） ] （2, C8H17N2 = N-ethyl-1,4-diazabicyclo[2.2.2] octane）, were synthesized under solvothermal conditions based on in situ ligand reaction and characterized via elemental analysis, XRD and single crystal X-ray diffraction analysis. Complex 1 crystallizes in the triclinic system, space group P1^- with a =0.74281（15） nm, b =0.84241（17） nm, c =0.9993（2） nm, α =82.02（3）°, β = 83.30 （3） °, γ = 82.92 （ 3 ） °, V = 0. 6114 （2） nm^3. Complex 2 crystallizes in the monoclinic system, space group P21/c with a =0.68924（14） nm, b = 1. 0786（2） nm, c =2. 2779（5） nm, β =94.84（3）°, V = 1. 6874（6） nm^3. Two kinds of in situ ligand reaction were found in the synthesis of these complexes. （C6H8N3 ） ^＋ ligand was synthesized from 2-aminopyrimidine and ethanol in complex 1, whereas （C8 H17 N2 ）^ ＋ ligand was synthesized from 1,4-diazabicyclo [ 2.2.2 ] octane and ethanol in complex 2.
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