采用振动弦黏度/密度计对碳酸二甲酯的黏度与密度进行了实验研究,测量的温度范围为283-353K,压力范围为0.1—20MPa。实验系统黏度和密度测量的不确定度分别为±2%和±0.2%。利用得到的实验数据,分别拟合了碳酸二甲酯黏度和密度的关联方程。黏度实验数据与方程的平均绝对偏差为0.47%,最大绝对偏差为2.06%;密度实验数据与方程的平均绝对偏差为0.04%,最大绝对偏差为0.14%。最后将实验数据与文献数据进行了比较。为碳酸二甲酯作为替代燃料等研究提供了基础数据。
Measurements of the viscosity and density of dimethyl carbonate are reported at temperatures from 283 to 353 K and at pressures up to 20 MPa. The measurements were performed simultaneously using a vibrating-wire instrument operated in the forced mode of oscillation. The overall uncertainties of these results are ±2.0% in viscosity and ±0.2% in density. The measurements were correlated with Tait-type equation for density and Hard-sphere scheme for viscosity. The average absolute deviation and the maximum absolute deviation of the viscosity measurements from the correlation for dimethyl carbonate are 0.47% and 2.06%, respectively. With regard to density, the average absolute deviation and the maximum absolute deviation of the present results from the correlation are 0.04% and 0.14%, respectively. Comparisons of the experimental data and measurements from literatures with the values calculated by the correlations at different temperatures and pressures are presented.