将BiGaO3和BiInO3分别引入BiScO3-Pb—TiO3(BSPT)体系,并通过氧化物合成法制备了0.075BiGaO3-(0.925-z)BiScO3-xPbTiO3(BGSPTx,x=0.58~O.62)和0.075BilnO3-(0.925-x)BiScO3-xPb-TiO3(BISPTx,x=0.61~0.65)压电陶瓷。X射线衍射分析表明,BiGaO。和BilnO。的替换掺杂均不影响BSPT体系的钙钛矿结构。随着PbTiO3含量的增加,BGSPTx和BISPTx陶瓷由三方钙钛矿结构逐渐变到四方结构,其三方-四方准同型相界分别位于x=0.60和x=0.62附近。在准同型相界附近,BGSPT。陶瓷的压电常数d33,机电耦合系数kp为分别为350pC/N和52.0%,而BISPT。的d33高达475pC/N,kp为52.3%。介电常数的温度特性测试表明,掺入Ga抖可以有效地提升BSPT体系的居里温度,其MPB组分(x=0.60)居里温度高达472℃,而掺入In^3+对BSPT体系的居里温度影响则不明显。
Ceramics of 0. 075BiGaO3-(0. 925- x)BiScO3-xPbTiO3 (BGSPTx, x = 0. 58-0. 62 ) and 0. 075BiInO3- (0. 925-x)BiScO3-xPbTiO3 (BISPTx, x=0. 61-0. 65) were prepared by conventional solid state reactions when BiGaO3 and BiInO3 was doped into BiScO3-PbTiOx (BSPT) system, respectively. The analysis results of X-ray diffraction reveals that BGSPTx and BISPTx posses single perovskite structure, in which MPB between tetragonal to rhombohedral phase transformation appears for BGSPTx,x=0.60 and BISPTx, x=0.62 respectively. Samples close to MPB gave piezoelectric and electromechanical coupling coefficients of BGSPTx about 350pC/N and 52.0%, respectively, comparing of BISPTx about 475pC/N and 52.3 %, respectively. The results of dielectric permittivity versus temperature proved that the introduction of Ga^3+ into BSPT system really increased the Tc of BSPT(x=0.60, Tc =472℃) ceramics,but the same result was not observed for introduction of In^3+ into BSPT system.