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中文摘要：
受体分子的多维多层次分子组装及功能是超分子化学的核心研究内容。该项目以具有不同功能基团的环状分子为受体，主要包括修饰环糊精、杯状化合物、脲基大环等为构筑单元，利用协同组装方法将它们组装在同一个超分子结构中，构筑具有优良性能和生物功能的多维多层次超分子组装体，运用各种现代测试技术研究多维多层次超分子组装体的形成规律和驱动力，阐明多种分子间非共价相互作用的内在联系和协同效果，从小分子到多维多层次超分子组装体的化学反应过程、构效关系以及特殊的理化性质等基础科学问题。通过对组装方法的优化实现对多维多层次超分子组装体的结构、尺寸、形貌的控制，通过引入不同修饰基团和外界因素如光照、温度、pH或电化学等实现对多维多层次超分子组装体功能的调控。提供多种具有优良性能和生物功能的多维多层次超分子组装体，并在此基础上揭示新现象，发展新理论，开拓新技术。
英文摘要：
cyclic molecular receptor；multiple dimensional；molecular assembly；driving force；supramolecular chemistry
结论摘要：
受体分子的多维多层次分子组装及功能是超分子化学的核心研究内容。该项目以具有不同功能基团的环状分子为受体，主要包括修饰环糊精、杯状化合物、脲基大环等为构筑单元，利用协同组装方法将它们组装在同一个超分子结构中，构筑具有优良性能和生物功能的多维多层次超分子组装体，运用各种现代测试技术研究多维多层次超分子组装体的形成规律和驱动力，阐明多种分子间非共价相互作用的内在联系和协同效果，从小分子到多维多层次超分子组装体的化学反应过程、构效关系以及特殊的理化性质等基础科学问题。通过对组装方法的优化实现对多维多层次超分子组装体的结构、尺寸、形貌的控制，通过引入不同修饰基团和外界因素如光照、温度、pH 或电化学等实现对多维多层次超分子组装体功能的调控。项目共发表和接收SCI论文115篇，申请专利19项。
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期刊论文
Novel Pillar[5]arene-Based Dynamic Polyrotaxanes Interlocked by the Quadruple Hydrogen Bonding Ureid
One dimensional infinite water wires incorporated in isostructural organic crystalline supermolecule
A Heterowheel [3]Pseudorotaxane by Integrating beta-Cyclodextrin and Cucurbit[8]uril Inclusion Compl
Electrochemical stimulus-responsive supramolecular polymer based on sulfonatocalixarene and viologen
Synthesis of perylene-bridged bis(dibenzo-24-crown-8) and its assembly behavior with a fullerene-bas
p-Sulfonatocalix[4]arenes Supramolecular Polymers: Formation by Host-Guest Interactions and Light Re
Synthesis of cyclotriveratrylene-phenylacetylene derivatives and a photophysical investigation of ri
Molecular Binding Behaviors between Tetrasulfonated Bis(m-phenylene)-26-crown-8 and Bispyridinium Gu
Novel Prolinamide Organocatalysts Based on Calix[4]arene Scaffold for the Enantioselective Direct Al
A Double-Leg Donor-Acceptor Molecular Elevator: New Insight into Controlling the Distance of Two Pla
Characterisation and antiproliferative activity of irinotecan and sulphonatocalixarene inclusion com
Operational calixarene-based fluorescent sensing systems for choline and acetylcholine and their app
Topochemical photodimerization of (E)-3-benzylidene-4-chromanone derivatives from beta-type structur
Intergrown New Zeolite Beta Polymorphs with Interconnected 12-Ring Channels Solved by Combining Elec
Thermodynamic origins of selective binding affinity between p-sulfonatocalix[4,5]arenes with biguani
Multistimuli Responsive Supramolecular Vesicles Based on the Recognition of p-Sulfonatocalixarene an
Complexation of p-Sulfonatocalixarenes with Local Anaesthetics Guests: Binding Structures, Stabiliti
Molecular Binding and Assembly Behavior of beta-Cyclodextrin with Piperazine and 1,4-Dioxane in Aque
Synthesis, structure, fullerene-binding and resolution of C-3-symmetric cavitands with rigid and dee
Crystalline Self-Assembly of a Bowl-Like Cyclotriguaiacylene Derivative with Alcohol/Phenols by Hydr
Design and construction of an organic crystal with a novel interpenetrated n-Borromean linked topolo
Stepwise tuning of the substituent groups from mother BTB ligands to two hexaphenylbenzene based lig
Observation of a Persistent Supramolecular Synthon Involving Carboxyl Groups and H2O That Guides the
Improved recognition of alkylammonium salts by ion pair recognition based on a novel heteroditopic p
Construction of a Supramolecular Polymer by Bridged Bis(permethyl-beta-cyclodextrin)s with Porphyrin
Selectively Fluorescent Sensing Behavior of Phenylaza-15-crown-5-triazolyl Coumarin for Hg2+ and Fe3
Dual-Stimulus Luminescent Lanthanide Molecular Switch Based on an Unsymmetrical Diarylperfluorocyclo
Enzyme-responsive supramolecular polymers by complexation of bis(p-sulfonatocalixarenes) with subery
Supramolecular binary hydrogels from calixarenes and amino acids and their entrapment-release of mod
Construction and Efficient Radical Cation Stabilization of Cyclodextrin/Aniline Polypseudorotaxane a
Effective Enlargement of Fluorescence Resonance Energy Transfer of Poly-Porphyrin Mediated by beta-C
Quinolinotriazole-beta-cyclodextrin and its adamantanecarboxylic acid complex as efficient water-sol
Novel Macrocycles Bearing Dithienylethene Units and Urea Functional Groups: Synthesis, Structure and
Pillar[5]arene-based supramolecular polypseudorotaxane polymer networks constructed by orthogonal se
Square-Planar Palladium Complexes with Trans Di- and Tribenzylphosphine Ligands Bearing O(CH2)(4)CH=
Binaphthyl-bridged bis-imidazolinium salts as N-heterocyclic carbene ligand precursors in the pallad
Construction of a Graphene Oxide Based Noncovalent Multiple Nanosupramolecular Assembly as a Scaffol
Guest releasing from solution to solid-state triggered by cyclomaltohexaose (alpha-cyclodextrin) agg
High Affinity Crown Ether Complexes in Water: Thermodynamic Analysis, Evidence of Crystallography an
Molecular Binding Behaviors of Pyromellitic and Naphthalene Diimide Derivatives by Tetrasulfonated 1
Novel self-assembled dynamic [2]catenanes interlocked by the quadruple hydrogen bonding ureidopyrimi
Construction and transmembrane dissociation behavior of supramolecular assembly of quinolinocyclodex
Spatially Controllable DNA Condensation by a Water-Soluble Supramolecular Hybrid of Single-Walled Ca
Controlled Photophysical Behaviors between Dibenzo-24-crown-8 Bearing Terpyridine Moiety and Fullere
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