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中文摘要：
本研究项目以无机材料氧化铝、硅胶和六方相中孔分子筛MCM-41、有机-无机杂化笼状多面体硅氧烷寡聚物（POSS），和有机聚合物材料聚苯乙烯(含1-2% DVB)等为载体，其载体表面官能团与含有双活性官能团试剂的其一官能基通过键合反应接枝修饰，其另一官能基与脯氨酸或由含多个脯氨酸构成的寡肽在肽偶联剂的存在下通过酰胺键的生成获得载体接枝的脯氨酸和含脯氨酸寡肽催化剂；另外载体催化剂亦可以采用固相肽偶联逐步合成法来制备。以制备的载体催化剂Direct Catalytic Asymmetric Aldol, Mannich, Michael, Diels-Alder, α-Amination of Aldehydes (Ketones) and One-Pot Multicomponent Reactions 等以评价其效果；并应用于天然产物和环状化合物的不对称合成中。
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期刊论文
Silica Gel Supported Pyrrolidine-based Chiral Ionic Liquid as Recyclable Organocatalyst for Asymmetr
A Highly Efficient and Recyclable Ionic Liquid-Anchored Pyrrolidine Catalyzed Enantioselective Micha
Iron-Catalyzed Ligand-Free Three-Component Coupling Reactions of Aldehydes, Terminal Alkynes, and Am
Silica Immobilized NHC–CuI: An Efficient and Reusable Catalyst for A3-Coupling (Aldehyde–Alkyne–Amin
Silica-Anchored Proline-Copper(I) as an Efficient and Recyclable Catalyst for the Sonogashira Reacti
Chiral Ionic Liquid Containing L-Proline Unit as a Highly Efficient and Recyclable Asymmetric Organo
Amination Reactions of Aryl Halides with Nitrogen-containing Reagents Catalyzed by CuI in Ionic Liqu
One-Pot Synthesis of 1,2,3-Triazoles from Benzyl and Alkyl Halides, Sodium Azide and Alkynes in Wate
Asymmetric Aldol Reactions Catalyzed by Efficient and Recyclable Silica-supported Proline-based Pept
Polystyrene-Iimmobilized Pyrrolidine as a Highly Stereoselective and Recyclable Organocatalyst for A
Highly Efficient and Recyclable Palladium Catalyst Anchored on Organic-Inorganic Hybrid Material: Ap
SiO2–NHC–Cu(I): An Efficient and Reusable Catalyst for [3+2] Cycloaddition of Organic Azides and Ter
Polymer Immobilized Pyrrolidine-based Chiral Ionic Liquids as Recyclable Organocatalysts for Asymmet
Task-specific Ionic Liquid as Base, Ligand and Reaction Medium for the Palladium-catalyzed Heck Reac
Ti-MCM-41 supported phosphotungstic acid: An effective and environmentally benign catalyst for epoxi
Immobilized Palladium on Organic–Inorganic Hybrid Materials: a Novel and Reusable Catalyst for the C
Merrifield Resin Supported Dipeptides: Efficient and Recyclable Organo- catalysts for Asymmetric Ald
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