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中文摘要：
设计合成一系列新结构的吡啶氨基后过渡金属配合物、亚胺配体后过渡金属配合物和单茂基过渡金属配合物作为烯烃聚合催化剂。通过调节催化剂配体的立体位阻、推拉电子效应以及过渡金属种类，从而调节控制烯烃单体插入速率常数Kins和催化中心链行走速率常数Kw，使得能够在催化烯烃聚合过程中控制链的增长和催化活性中心沿增长链行走的方式。结合催化聚合条件和烯烃单体的变化的控制，达到制备不同拓扑结构的支化和可控组成的聚烯烃的目的。研究工作将对推动更深入系统的烯烃配位聚合基础研究具有重要的意义，同时也为拓宽新结构和新性能聚烯烃品种提供基本的依据。
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期刊论文
Longstanding Living Polymerization of Ethylene: Substituent Effect on Bridging Carbon of 2-Pyridinem
Polymerization of 4-Methyl-1-Pentene Catalyzed by (-Diimine Nickel Catalysts: Living/Controlled Beha
Complex Branched Polyolefin Generated from Quasi- Living Polymerization of 4-Methyl-1-Pentene Cataly
Living/controlled polymerization of 4-methyl-1- pentene with α-diiminenickel-diethylaluminium chlori
Synthesis and Characterization of a Series of 2-Aminopyridine Nickel(II) Complexes and Their Catalyt
Bis(?-Ketoamino)copper(II)/ Methylaluminoxane Systems for Homo- and Copolymerizations of Methyl Acry
Syntheses, Structures and Catalytic Ethylene Oligomeri zation Behaviors of Bis(phosphino)amine Nicke
Nickel and Palladium Complexes Bearing Ortho- Phenoxy Modified Anilido-Imine Ligands: Drastic Steric
Novel Bis(benzoin) Titanium Catalyst for Homo- and Copolymerization of Norbornene with Ethylene: Syn
2-Aminomethylpyridine Nickel (II) Complexes —Synthesis，Molecular Structure and Catalysis of Ethylene
Double-crystalline polyethylene-b-poly(ethylene oxide) with a linear polyethylene block: Synthesis a
Ionic Liquid-Supported Bis-(salicylaldimine) Nickel Complexes: Robust and Recyclable Catalysts for E
Nickel complexes bearing [N, N] 2-pyridylbenzamidine ligands: syntheses, characterizations, and cata
Neutral nickel complexes chelating monoamidinate ligands: Syntheses, characterizations and catalytic
Biphasic oligomerization of ethylene with nickel complexes immobilized in organochloroaluminate ioni
Vinyl Polymerization of Norbornene with Pyrazolyl mine Nickel(II)/ Methylaluminoxane Catalytic Syste
Dinuclear nickel (II) complexes bearing two pyrazolyli mine ligands: Synthesis characterization, and
High norbornene incorporation in ethylene-norbornene copolymerization with a bis((-alkyloxoimine) ti
Synthesis and Self-Assembly of New Double-Crystalline Amphiphilic Polyethylene-block-Poly[oligo(ethy
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