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中文摘要：
本项目探索分子内氢键（及配位作用等）驱动的分子折叠体内电子及能量活化基团的定位和相应的电子转移和能量传递的控制等，发展共性的非共价键原理以实现有机官能团在纳米尺度的分子内的定向组装，探索新的分子开关原理和方法等。我们设计了一系列新的寡聚苯甲酰胺和肼酰胺，在分子的两端分别并入卟啉（电子供体）和富勒烯(电子受体)等，通过分子内氢键控制分子骨架的构象，通过寡聚物的长度控制卟啉及富勒烯等活化官能团之间的距离，从而达到控制二者之间电子转移和能量传递速度和效率的目的。通过氨基的质子化和去质子化、引入和消除分子内氢键，达到调控分子骨架构象和官能团之间距离的目的。
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期刊论文
N-Unsubstituted and N-Arylated Fulleropyrrolidines: New Useful Building Blocks for C60 Functionaliza
Self-Assembly of Hydrazide-Based Heterodimers Driven by Hydrogen Bonding and Donor-Acceptor Interact
Hydrogen Bonded Semi-Rigidified Bispyridine-Incorporating Aryl Amide Oligomers: Efficient “C”-Styled
F(((H(N and MeO(((H(N Hydrogen-Bonding in the Solid States of Aromatic Amides and Hydrazides. A Comp
‘Two-point’-bound supramolecular complexes from semi-rigidified dipyridine receptors and zinc porphy
Complexation of hydrogen bonding-driven preorganized di- and hexacationic porphyrin receptors for C6
Helicity Induction in Hydrogen Bonding-Driven Zinc Porphyrin Foldamers by Chiral C60-Incorporated Hi
Strong Stacking between Hydrogen Bonded Foldamers and Fullerenes: Formation of Supramolecular Nano N
The N(H(((X (X = Cl, Br and I) Hydrogen Bonding in Aromatic Amides: A Crystallographic and 1H NMR St
Hydrogen Bonding-Directed Multicomponent Dynamic Covalent Assembly of Mono-, Bi- and Trimacrocycles.
Hydrogen Bonded Aryl Amide Macrocycles: Synthesis, Single-Crystal Structures, and Aromatic Interacti
Foldamer Organogels: A Circular Dichroism Study of Glucose-Mediated Dynamic Helicity Induction and A
Hydrogen Bonding-Induced Aromatic Oligoamide Foldamers as Spherand Analogues to Accelerate the Hydro
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