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有机体系中非氧化物功能材料制备及形成机理
  • 项目名称：有机体系中非氧化物功能材料制备及形成机理
  • 项目类别：重点项目
  • 批准号：20431020
  • 申请代码：B01
  • 项目来源：国家自然科学基金
  • 研究期限：2005-01-01-2008-12-31
  • 项目负责人：钱逸泰
  • 负责人职称：教授
  • 依托单位：中国科学技术大学
  • 批准年度：2004
中文摘要：

本申请旨在发展有机体系中碳化物、氮化物、硼化物以及含碳、氮或硼的无机化合物功能材料制备技术和研究其形成机理,也将继续研究III-V、II-VI族化合物等非氧化物功能材料在有机体系中的合成、形状控制与晶体生长。非氧化物功能材料有巨大的应用价值和发展前景，依据一些单质、化合物在有机体系中具有一定溶解度，选择特定的有机体系，通过控制温度、压力、时间等因素,合成非氧化物纳米晶功能材料和在适当的条件下生长成为尺寸较大的晶体。拟通过溶剂热、复合溶剂热、催化溶剂热、高温高压反应、回流或室温反应以及能量辐射等多种控制手段，设计无机反应路线和优化制备条件，实现材料的控制合成，制备出物相、形状、尺寸可控的非氧化物一维纳米线、管、带、线圈、空心球等纳米结构，为纳米器件的制备打下基础。研究有机体系中非氧化物功能材料的晶体生长，遴选普遍适用的生长方法，对一些重要的非氧化物功能材料的形成在热力学和动力学上加以解释。

中文主题词： 非氧化物; 纳米材料; 控制合成; 有机体系; 晶体生长
成果综合统计
成果类型
数量
  • 期刊论文
  • 会议论文
  • 专利
  • 获奖
  • 著作
  • 194
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  • 0
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  • 2
期刊论文
Synthesis and structure of a novel microporous gallium phosphate Ga3P2O8(OH)3(H2O) containing [34448
Prediction of open-framework aluminophosphate structures using the automated assembly of secondary
In Situ Synthesis, Magnetic Property, and Formation Mechanism of Fe3O4 Particles Encapsulated in 1D
Fabrication and Characterization of Ultralong Ag/C Nanocables, Carbonaceous Nanotubes, and Chainlike
Synthesis of multi-shell carbon microspheres
A convenient catalytic approach to synthesize straight BN nanotubes using synergic nitrogen source
High-yield synthesis of single-crystalline 3C–SiC nanowires by a facile autoclave route
Synthesis, structure, and magnetic property of a new open-framework manganese borophosphate, [NH4]4[
Solid-state NMR spectroscopy of anionic framework aluminophosphates: A new method to determine the
Fabrication of super-hydrophobic and super-oleophilic boehmite membranes from anodic alumina oxide f
Syntheses and characterizations of three low-dimensional chloride-rich zincophosphates assembled abo
Synthesis and characterization of a new layered fluoroaluminophosphate (C4H11NOH)3.5[Al4(PO4)5F] ? 0
Palladium-catalyzed double annulations to construct multisubstituted benzodifurans
Computational simulation study towards the synthesis of extra-large microporous materials
Sulfur-Assisted Approach for the Low-Temperature Synthesis of β-SiC Nanowires
Additive-Assisted Nitridation to Synthesize Si3N4 Nanomaterials at a Low Temperature
Synthesis and characterization of carbon fibrils formed by stacking graphite sheets of nanometer thi
Low-temperature solvothermal route to 2H-SiC nanoflakes
A Germanate Built from a 68126 Cavity Cotemplated by an (H2O)16 Cluster and 2-Methylpiperazine
Growth of PbS crystals from nanocubes to eight-horn-shaped dendrites through a complex synthetic rou
Controlled synthesis of trigonal selenium crystals with different morphologies
A simple biomolecule-assisted hydrothermal approach to antimony sulfide nanowires
Single-source approach to the synthesis of In2S3 and In2O3 crystallites and their optical properties
Single-crystalline alpha silicon-nitride nanowires: Large-scale synthesis, characterization, and opt
Hydrothermal growth and optical properties of doughnut-shaped ZnO microparticles
Low temperature synthesis of NbB2 nanorods by a solid-state reaction route
Isostructural Cd3E2 (E = P, As) microcrystals prepared via a hydrothermal route
Carbon nanofibers: Synthesis, characterization, and electrochemical properties
Shape-controlled synthesis and formation mechanism of nanoparticles-assembled Ag2S nanorods and nano
Hydrothermal synthesis and characterization of ZnS microspheres and hollow nanospheres
Surfactant-assisted hydrothermal route to organometallic tris(8-hydroxyquinoline)aluminum nanorod bu
Shape-controlled synthesis of tellurium 1D nanostructures via a novel circular transformation mechan
Hydrothermal synthesis of V0.13Mo0.87O2.935 nanowires with strong blue photoluminescence
Synthesis, characterization, and luminescence properties of uniform Ln(3+)-doped YF3 nanospindles
Malate-assisted synthesis of ZnO hexagonal architectures with porous characteristics and photolumine
Synthesis of kelp-like crystalline beta-SiC nanobelts and their apical growth mechanism
Tunable synthesis of various Wurtzite ZnS architectural structures and their photocaltalytic propert
A simple hydrothermal route to large-scale synthesis of uniform silver nanowires
Growth of microtubular complexes as precursors to synthesize nanocrystalline ZnS and CdS
Synthesis and characterization of [M(en)3][GeF6] (M=Ni,Co) with H-bonded pseudo-channel structure
Hydrothermal synthesis and characterization of a new two-dimensional Lanthanum(Ⅲ)-cobalt(Ⅱ)heteromet
Hydrothermal synthesis and characterization of a new layered fluoroaluminophosphate [C4H12N2][Al2(P
Hydrothermal synthesis and crystal structure of a new bimetallic oxide cluster constructed from β –o
Hydrothermal synthesis and characterization of a manganese(Ⅱ)-substituted aluminum phosphate Mn3Al6
Theoretical study on structures of EU-1 and ZSM-50 with EUO zeo-type
Molecular simulation of Mn(Ⅱ)-substituted aluminophosphate MnAPO-14
Synthesis and characterization of metalloborophosphates with zeotype ANA framework by the boric acid
[C3N2H12]·[MnAl3P4O17]·[H3O]: A manganese (II)-substituted aluminophosphate with zeotype AFN topolog
Towards rational synthesis of microporous aluminophosphate AlPO4-21 by hydrothermal combinatorial ap
A new open-framework structure of nickel complex pillared aluminophosphate [C6N4H20]2[Ni(Al3P4O16)2]
[H3N(CH2)4NH3]2[Al4(C2O4)(H2PO4)2(PO4)4]·4[H2O]: A new layered aluminum phosphate-oxalate
Two 2-D 36 tessellated metal-organic frameworks constructed from trimetallic clusters and dicarboxyl
One-pot catalytic solvothermal approach for carbon nanofibers preparation
Controlled synthesis and possible formation mechanism of leaf-shaped SnS2 nanocrystals
Growth of ZnS microfans and nanosheets: Controllable morphology and phase
Synthesis of nanocrystalline boron carbide via a solvothermal reduction of CCl4 in the presence of a
Unexpected Photoelectronic Effect from [Co(en)3]2(Zr2F12)(SiF6)·4H2O, a compound of H-bonded Assembl
Template-mediated growth of Cu3SnS4 nanoshell tubes
[Ni(1,2-PDA)3]2(HOCH2CH2CH2NH3)3(H3O)2[Ge7O14X3]3 (X=F, OH): A new 1-D germanate with 12-ring hexago
Preparation and characterization of near-infrared luminescent bifunctional core/shell nanocomposites
A novel route to hollow and solid carbon spheres
Synthesis of multi-walled carbon nanotubes at low temperature through anhydrous AlCl3-assisted ethyl
Structure and Luminescence of 2D Dilute Magnetic Semiconductors: Cd1-xMnxSe·L0.5 (L = Diamines)
Growth of Cu2S ultrathin nanowires in a binary surfactant solvent
Preparation and characterization of layered zirconium phosphates based on water-in-oil microemulsion
Synthesis of wurtzite ZnS nanowire bundles using a solvothermal technique
Synthesis and shape evolution of bismuth selenide hollow nanospheres
Nitridation of silica to an alpha-silicon nitride nanorod using NaNH2 in the autoclave at 700 degree
Solvothermal synthesis, structure and mossbauer spectroscopy of a new mixed-valence iron aluminophos
Ni11As8 single-crystalline nanosheets via hydrothermal redox route
Low-temperature synthesis and growth mechanism of uniform nanorods of bismuth sulfide
Synthesis, characterization, and growth mechanism of tellurium nanotubes
A new nickel complex-templated layered aluminophosphate [Ni(C4N3H13)(C4N3H14)H2O][Al3P4O16]
A simple route for the synthesis of coral-like accretion of hollow carbon microspheres with thin wal
Syntheses, structures, ionic conductivities, and magnetic properties of three new transition-metal b
Dedicated to Professor Ruren Xu on the Occasion of his 75th birthday – Preface
C6H10N3O2 [Zn2(HPO4)(PO4)]·H2O:An Inorganic Network with Biofunctional Amino Acid D, L-Histidine Mol
Structure and magnetic properties of a Two-dimensional layered manganese(Ⅱ) pyrophosphate [NH4]2[Mn3
Design of chiral zeolite frameworks with specified channels through constrained assembly of atoms
Lamellar mesostructured aluminophosphates: Intercalation of n-alkylamines into layered aluminophosph
Synthesis, structure, and luminescent property of a heterometallic metal-organic framework cons
Assembly of Helical Hydrogen Bonds in a New Layered Aluminophosphate [C6N3H17][Al2(HPO4)(PO4)2]
Insight into the construction of open-framework aluminophosphates
[(C4H12N)2][Zn3(HPO3)4]: An open-framework zinc phosphite containing extra-large 24-ring channels
A Facile Approach for the Synthesis of Uniform Hollow Carbon Nanospheres
Solvothermal synthesis of Si3N4 nanomaterials in low temperature
Synthesis and characterization of superconducting NbC nanotubes
Mg-catalyzed autoclave synthesis of aligned silicon carbide nanostructures
Transformations of a layer and a chain aluminophosphates to the zeotype |Al-P-M-O|-GIS (M = Co2+, Mn
Na2.4CeSi6O15?2.6H2O: Hydrothermal Synthesis, Characterization and Properties of a New Luminescent M
Fabrication of superhydrophilic Cu2O and CuO membranes
Structural investigation of layered aluminophosphate UT-4 by solid-state NMR
Rapid synthesis and morphology control of silicalite-1 crystals by microwave-assisted solvothermal s
Microemulsion-directed synthesis of zeolite A nano-crystals
Introduction and application of zeobank: zynthesis and structure databases of zeolites and related m
Three metal-organic frameworks prepared from mixed solvents of DMF and HAc
Synthesis and characterization of a new open-framework aluminophosphate C4N3H16Al4P5O20(H2O)2 (AlPO-
Chiral Recognition of Mesoporous SBA-15 with an Incorporated Chiral Porphyrin
[C4N2H12]2[In3(HPO4)5(H2PO4)F2]: The first 2-D fluorinated indium phosphate with double-sheet layers
[Ni(C6N2H14)2][Zn4(H2O)(HPO3)5]: A new open-framework zinc phosphite with intersecting 8-, 12- and 1
Polymer-assisted synthesis of Co2P nanocrystals
Sulphur-assisted Synthesis of Silicon Nitride Nanorods in Autoclaves at 250 oC
Morphology Changes of Transition-Metal-Substituted Aluminophosphate Molecular Sieve AlPO4-5 Crystals
An efficient synthesis of fused tricycles with a benzene core via intramolecular double ring-closing
Solvothermal synthesis and structure of a neutral layered borate B3O4(OH)(C4N2H10)0.5 containing hel
A family of luminescent microporous lanthanide silicates
Convenient fabrication and property investigations of uniform TiN hollow nanocages
Selective synthesis of 3C-SiC hollow nanospheres and nanowires
Synthesis, characterization and properties of novel BN nanocages from a single-source precursor
A co-reduction-silicification route to delta-Ni2Si nanowire
One convenient synthesis route to boron nitride nanotube
Solvothermal synthesis of NiS 3D nanostructure's
Selective fabrication of metastable greigite (Fe3S4) nanocrystallites and its magnetic properties th
Synthesis and characterization of nanocrystalline TaN
One-dimensional chain Fe3O4 nanoparticles encapsulated in worm-shaped carbon shell
Hydrothermal growth and morphology modification of beta-NiS three-dimensional flowerlike architectur
Synthesis and characterization of nitrogen-rich graphitic carbon nitride
Synthesis at 250 degrees C of submicron hydrogenated amorphous carbon "test tubes"
Phase transition of CdSe nanocrystallines with controlled morphologies induced by ratios of ethanola
GaN taper rods: Solid-phase synthesis, crystal defects, and optical properties
Glucose-assisted synthesis of CoTe nanotubes in situ templated by Te nanorods
Synthesis and characterization of larger diameter carbon nanotubes from catalytic pyrolysis of polyp
Preparation and characterization of cubic and hexagonal polytypes of ZnSe : Cu2+ one-dimensional nan
A self-assembly template approach to form hollow hexapod-like, flower-like and tube-like carbon mate
A core-shell nanostructure of carbon
Synthesis of whisker-like boron nitride by a diamine thermal method
Low-temperature synthesis of nanocrystalline niobium nitride via a benzene-thermal route
Synthesis and oxidation behavior of nanocrystalline niobium carbide
Low-temperature synthesis and benzene-thermal growth of nanocrystalline boron nitride
A Precursor-based route to ZnSe Nanowire Bundles
Solvothermal synthesis of CdS nanowires in a mixed solvent of ethylenediamine and dodecanethiol
Crystalline silicon carbide nanoparticles encapsulated in branched wavelike carbon nanotubes: Synthe
A precursor decomposition route to polycrystalline CuS nanorods
Solvothermal synthesis of single crystalline ZnTe nanorod bundles in a mixed solvent of ethylenediam
A facile method to the cube-like MnSe2 microcrystallines via a hydrothermal process
Synthesis and characterization of alpha-MnS polyhedrons and spheres
A solvothermal route to semiconductor ZnS micrometer hollow spheres with strong photoluminescence pr
Formation of CdSe nanorod-assembled microtubes in an ethanolamine-PEG solution
Large-scale synthesis, growth mechanism, and photoluminescence of ultrathin Te nanowires
A facile route to VN and V2O3 nanocrystals from single precursor NH4VO3
A hydrothermal reduction route to single-crystalline hexagonal cobalt nanowires
The fabrication and characterization of single-crystalline selenium nanoneedles
Double-source approach to In2S3 single crystallites and their electrochemical properties
Large-scale synthesis and growth mechanism of single-crystal Se nanobelts
Control to synthesize Bi2S3 nanowires by a simple inorganic-surfactant-assisted solvothermal process
Synthesis of helically coiled carbon nanotubes by reducing ethyl ether with metallic zinc
The synthesis and structure of a chiral 1D aluminophosphate chain compound: d-Co(en)(3)[AlP2O8]·6.5H
Shape-controlled synthesis of 3D and 1D structures of CdS in a binary solution with L-cysteine's ass
Synthesis and optical properties of cubic In2S3 hollow nanospheres
Double annulations of dihydroxy- and diacetoxydialkynylbenzenes.An efficient construction of benzodi
Host guest compound: Synthesis, characterization and single crystal X-ray structural study of [Co(NH
A simple nitrification route to nanocrystalline CrN
New ZnS/organic composite nanoribbons: characterization, thermal stability and photoluminescence
Synthesis of tungsten carbide nanocrystal via a simple reductive reaction
Hierarchical growth and shape evolution of HgS dendrites
Self-assembled copper nanowalls into microstructures with different shapes: A facile aqueous approac
Aqueous solution route to flower-like microstructures of ferromagnetic nickel nanotips
Single-source approach to cubic FeS2 crystallites and their optical and electrochemical properties
Size-controllable growth of single crystal In(OH)(3) and In2O3 nanocubes
Solution-phase synthesis and high photocatalytic activity of wurtzite ZnSe ultrathin nanobelts: A ge
Controlled synthesis of carbon nanocables and branched-nanobelts
Thermal analyses of various alkylamines-templated aluminophosphate AlPO4-21
Synthesis and characterization of two new open-framework zinc phosphites [M(C6N4H18)][Zn3(HPO3)4](M=
Chiral layered zincophosphate [d-Co(en)3]Zn3(H0.5PO4)2(HPO4)2 assembled about d-Co(en)33+ complex ca
Syntheses and structures of two low-dimensional beryllium phosphate compounds: [C5H14N2]2[Be3(HPO4)5
Synthesis, structure, and photoluminescence property of a new layered zirconium phosphate vertical b
Morphology control of self-stacked silicalite-1 crystals using microwave-assisted solvothemial synth
Solvothermal/hydrothermal route to semiconductor nanowires
Olivary particles: Unique carbon microstructure synthesized by catalytic pyrolysis of acetone
Na3TbSi3O9 center dot 3H2O: A new luminescent microporous terbium(III) silicate containing helical S
Na2[VB3P2O12(OH)]·2.92H2O: A New Open-Framework Vanadium Borophosphate Containing Extra Large 16-Rin
Roselike microstructures formed by direct in situ hydrothermal synthesis: From superhydrophilicity t
A low-temperature route for the synthesis of nanocrystalline LaB6
Synthesis and gas sensitivities of SnO2 nanorods and hollow microspheres
Solvothermal synthesis of carbon nanomaterials
A chemical co-reduction route to synthesize nanocrystalline vanadium carbide
碳、碳化硅及氮化硅等纳米功能材料的制备
Solvothermal preparation of amorphous carbon nanotubes and Fe/C coaxial nanocables from sulfur, ferr
Controllable synthesis of PbSe nanostructures and growth mechanisms
Fabrication of silicalite-1 crystals with tunable aspect ratios by microwave-assisted solvothermal s
Template-Designed Syntheses of Open-Framework Zinc Phosphites with Extra-Large 24-Ring Channels
Chiral Zeolitic Materials: Structural Insights and Synthetic Challenges
12H3O?[Co8(HPO3)9(CH3OH)3]?2H2O: An Open-Framework Cobalt Phosphite Containing Extra-Large 18-ring C
Cotemplating Ionothermal Synthesis of a New Open-Framework Aluminophosphate with Unique Al/P Ratio o
Tetraethylenepentamine-Directed Controllable Synthesis of wurtzite ZnSe Nanostructures with Tunable
会议论文
纳米材料化学制备的新技术、新方法研究
著作
Inorganic chemical reactions in organic systems?solvothermal process to prepare inorganic materials
Chemistry of zeolites and related porous materials-synthesis and structure
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