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中文摘要：
针对制约生物降解高分子发展的结构和性能控制两个瓶颈问题，以"生物降解高分子的合成与加工的基本科学问题"为研究方向，发挥群体在生物降解高分子材料领域的长期积累和综合优势，以聚乳酸、二氧化碳共聚物为主要研究对象，以5000吨/年聚乳酸和5000吨/年二氧化碳基塑料两条生产线为依托，以高分子链结构控制-凝聚态结构调控-加工流变学-材料热稳定性与力学性能为研究主线，重点开展4个方面的基础研究(1)结构可控聚合与催化剂；(2)生物降解高分子的结构与性能调控；(3)材料成型加工中的基本科学问题；(4) 生物降解高分子材料的非石油路线合成。从而解决生物降解高分子材料的核心原料来源、结构可控合成和性能控制等关键科学问题，使群体成为我国生物降解高分子材料的研发基地和降解塑料产业的核心技术源头，成为国际上在该领域具有一流水平的创新团队，为我国的低碳经济和可持续发展战略做出创新性贡献。
英文摘要：
biodegradable；polymer materials；high activity catalyst；structural control；polymer processing
结论摘要：
通过对合成生物降解高分子材料的高活性和高选择性催化剂、材料的一次结构和聚集态结构控制、材料的成型加工流变学等基本科学问题的系统研究，取得了一系列的创新性研究成果。发表143篇SCI收录的学术论文，使研究团队成为生物降解高分子领域有世界影响的一支力量；同时实现了二氧化碳基塑料和聚乳酸2大类生物降解高分子的规模化生产和应用，成为我国生物降解高分子材料产业的核心技术源头，为在我国建立具有世界竞争力、拥有核心技术的生物降解高分子产业做出了重要贡献。围绕着生物降解高分子材料的基本科学问题，研究群体按照计划开展了催化剂设计合成与结构可控聚合、生物降解高分子的结构与性能调控、生物降解高分子材料的改性和加工和非石油路线高分子材料的合成与改性等4个方面的研究工作，并取得了一系列的研究成果。除了按照既定目标积极开展工作以外，我们还积极开展生物降解高分子材料的多样化及应用拓展，成功实现了热响应性脂肪族聚（氨酯-胺）、生物可降解内毒素吸附材料、生物可降解聚合物/血红蛋白组装体的合成，并开展了高分子/药物自组装体系的稳定化与可控释放等研究。围绕全生物降解的二氧化碳基塑料(PPC)和聚乳酸（PLA）的合成与改性，系统研究了原料单体的合成与纯化、催化剂、聚合反应工艺、聚合后处理技术、聚合物改性与加工等全流程产业化关键技术，成功实现了3万吨/年二氧化碳基塑料生产线和5000吨/年聚乳酸生产线的稳定生产，形成了较为完备的二氧化碳基塑料和聚乳酸的产业化关键技术，正在积极推动我国乃至世界的生物降解塑料产业发展。
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期刊论文
Effect of a phosphorus-containing oligomer on flame-retardant, rheological and mechanical properties
Effects of acyl chloride monomer functionality on the properties of polyamide reverse osmosis (RO) m
Biodegradable pH-responsive polyacrylic acid derivative hydrogels with tunable swelling behavior for
Preparation and characterization of positively charged composite nanofiltration membranes by coating
Blends of Linear and Long-Chain Branched Poly(L-lactide)s with High Melt Strength and Fast Crystalli
Enhancing Molecular Conductance of Oligo(p-phenylene ethynylene)s by Incorporating Ferrocene into Th
NNN-Tridentate Pyrrolyl Rare-Earth Metal Complexes: Structure and Catalysis on Specific Selective Li
An Unusual Organoyttrium Alkyl Complex Containing a [C5HMe3(eta(3)-CH2)-C5H4N-kappa](-) Ligand and a
Highly Regio- and Stereoselective Terpolymerization of Styrene, Isoprene and Butadiene with Lutetium
Plasticizing while toughening and reinforcing poly(propylene carbonate) using low molecular weight u
Synthesis of novel cardo poly(arylene ether sulfone)s with bulky and rigid side chains for direct me
Cationic Dendron-Bearing Lipids: Investigating Structure-Activity Relationships for Small Interferin
Nanofiber-based poly(aryl ether sulfone) containing guanidinium groups as novel anion-exchange membr
Core-crosslinked amphiphilic biodegradable copolymer based on the complementary multiple hydrogen bo
Synthesis and characterization of novel cardo poly(aryl ether sulfone) bearing zwitterionic side gro
Chemosynthesis of Poly(epsilon-lysine)-Analogous Polymers by Microwave-Assisted Click Polymerization
Poly(arylene ether sulfone)s ionomers with pendant quaternary ammonium groups for alkaline anion exc
Novel side-chain-type cardo poly(aryl ether sulfone) bearing pendant sulfoalkyl groups for proton ex
Synthesis of Isotactic-Heterotactic Stereoblock (Hard-Soft) Poly(lactide) with Tacticity Control thr
Facile synthesis of pendant- and alpha,omega-chain-end-functionalized polycarbonates via immortal po
Facile synthesis of fluorescent dye labeled biocompatible polymers via immortal ring-opening polymer
Selective synthesis of oligo(carbonate-ether) diols from copolymerization of CO2 and propylene oxide
Facile Synthesis of Poly(ether carbonate)s via Copolymerization of CO2 and Propylene Oxide Under Com
Binuclear Rare-Earth-Metal Alkyl Complexes Ligated by Phenylene-Bridged beta-Diketiminate Ligands: S
Combination of Anti-Biofouling and Ion-Interaction by Click Chemistry for Endotoxin Selective Remova
Co-delivery of 10-Hydroxycamptothecin with Doxorubicin Conjugated Prodrugs for Enhanced Anticancer E
Mechanical, aging, optical and rheological properties of toughening polylactide by melt blending wit
Biodegradable CO2-Based Polycarbonates with Rapid and Reversible Thermal Response at Body Temperatur
Thermosensitive hydrogels based on polypeptides for localized and sustained delivery of anticancer d
Novel polymer electrolyte from poly(carbonate-ether) and lithium tetrafluoroborate for lithium-oxyge
Stereoselective Ring-Opening Polymerization of rac-Lactides Catalyzed by Aluminum Hemi-Salen Complex
Facile fabrication method of hydrophobic-associating cross-linking hydrogel with outstanding mechani
Morphology and properties of the biosourced poly(lactic acid)/poly(ethylene oxide-b-amide-12) blends
Yttrium Hydride Complex Bearing CpPN/Amidinate Heteroleptic Ligands: Synthesis, Structure, and React
Morphology and properties of biodegradable and biosourced polylactide blends with poly(3-hydroxybuty
Rare-Earth-Metal-Hydrocarbyl Complexes Bearing Linked Cyclopentadienyl or Fluorenyl Ligands: Synthes
Effect of crystallization on microstructure and mechanical properties of poly[(ethylene oxide)-block
Zinc complexes containing asymmetrical N,N,O-tridentate ligands and their application in lactide pol
The formation and transition behaviors of the mesophase in poly(D-lactide)/poly(L-lactide) blends wi
Reduction-responsive cross-linked micelles based on PEGylated polypeptides prepared via click chemis
Electrospun hydroxyapatite grafted poly(L-lactide)/poly(lactic-co-glycolic acid) nanofibers for guid
Rare-Earth-Metal Complexes Bearing Phosphazene Ancillary Ligands: Structures and Catalysis toward Hi
Synthesis and characterization of -amino acid-containing polyester: poly[(epsilon-caprolactone)-co-(
Water Dispersed Conducting Polyaniline Nanofibers for High-Capacity Rechargeable Lithium-Oxygen Batt
Toughening of poly(propylene carbonate) by hyperbranched poly(ester-amide) via hydrogen bonding inte
Biodegradable Amphiphilic Copolymer Containing Nucleobase: Synthesis, Self-Assembly in Aqueous Solut
Hydrophobically associated hydrogels based on acrylamide and anionic surface active monomer with hig
Dicarboxylic acid promoted immortal copolymerization for controllable synthesis of low-molecular wei
Synthesis of Poly(2-furyloxirane) with High Molecular Weight and Improved Regioregularity Using Macr
Ligand-Free Magnesium Catalyst System: Immortal Polymerization of L-Lactide with High Catalyst Effic
Functional microporous polyimides based on sulfonated binaphthalene dianhydride for uptake and separ
Magnesium and Zinc Complexes Supported by N,O-Bidentate Pyridyl Functionalized Alkoxy Ligands: Synth
A novel amphiphilic copolymer poly(ethylene oxide-co-allyl glycidyl ether)-graft-poly(epsilon-caprol
Copolymerization of Carbon Dioxide and Propylene Oxide under Inorganic Oxide Supported Rare Earth Te
Preparation of Poly(serine ester)s by Ring-opening Polymerization of N-Trityl Serine Lactone Under C
Thermosensitive polyion complex micelles prepared by self-assembly of two oppositely charged diblock
Nanoscaled Poly(L-glutamic acid)/Doxorubicin-Amphiphile Complex as pH-responsive Drug Delivery Syste
Aqueous Dispersed Conducting Polyaniline Nanofibers: Promising High Specific Capacity Electrode Mate
Thymine Modified Amphiphilic Biodegradable Copolymers for Photo-Cross-Linked Micelles as Stable Drug
Effects of molten poly(D,L-lactide) on nonisothermal crystallization in stereocomplex of poly(L-lact
Positively charged nanofiltration membrane based on cardo poly(arylene ether sulfone) with pendant t
The effect of alkyl side groups on the secondary structure and crystallization of poly(ethylene glyc
PLA-PEG-PLA and Its Electroactive Tetraaniline Copolymer as Multi-interactive Injectable Hydrogels f
Poly(arylene ether sulfone)s ionomers containing quaternized triptycene groups for alkaline fuel cel
A reduction-sensitive carrier system using mesoporous silica nanospheres with biodegradable polyeste
Rare-earth metal bis(alkyl)s that bear a 2-pyridinemethanamine ligand: Dual catalysis of the polymer
Crystallization, Mechanical Properties, and Enzymatic Degradation of Biodegradable Poly(epsilon-capr
A novel fabrication method of temperature-responsive poly(acrylamide) composite hydrogel with high m
Synthesis and characterization of triphenylamine-containing microporous organic copolymers for carbo
Scandium alkyl complex with phosphinimino-amine ligand: Synthesis, structure and catalysis on ethyle
Positively charged nanofiltration membrane formed by interfacial polymerization of 3,3 ',5,5 '-biphe
Synthesis and characterization of cross-linked poly(arylene ether ketone) containing pendant quatern
Synthesis and characterization of a novel poly(arylene ether sulfone) containing pendent imidazole g
Assembly of an unbalanced charged polyampholyte onto Nafion (R) to produce high-performance composit
PEGylated Click Polypeptides Synthesized by Copper-Free Microwave-Assisted Thermal Click Polymerizat
Facile preparation of core cross-linked micelles from catechol-containing amphiphilic triblock copol
Heteroscorpionate Rare-Earth Metal Zwitterionic Complexes: Syntheses, Characterization, and Heterose
Synthesis and stabilization of high-molecular-weight poly(propylene carbonate) from Zn-Co-based doub
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