欢迎您！东篱公司
退出
-
申报数据库
-
立项数据库
-
成果数据库
-
项目获奖数据库
位置：立项数据库 > 立项详情页
中文摘要：
规整、有序多孔薄膜和溶液中形成的两亲分子有序聚集体,作为新型组装（聚集）结构材料在化学、光学、生物医学等领域具有广泛的应用前景,近年来引起了科学家极大的关注，近年来得到了较快的发展。本项目旨在以性能优异的、表面活性剂或聚合物修饰的疏水性纳米颗粒（无机纳米尺度大分子、纳米Au、Ag等）为基本组装单元，组装具有生物功能的多层次、多尺度的有序多孔薄膜结构；开展溶液中形成的有序聚集体的结构、性质和性能研究，结合理论计算模拟，对组装（聚集）结构从分子水平上给出理论解释，提出新的聚集理论。主要研究内容（1）有序多孔薄膜组装的技术方法；（2）组装基元间存在的非共价键作用对多孔薄膜自组装的影响以及多尺度上的组装行为的本质；（3）溶液中聚集体的形成规律和外界条件创造并可控聚集体制备；（4）多孔薄膜复合材料以及聚集结构材料的生物效应，如细胞粘附和培育功能。
英文摘要：
molecule self-assembly；porous films；vesilces；non-covalent interaction；functions
结论摘要：
规整、有序多孔薄膜和溶液中形成的两亲分子有序聚集体,作为新型组装（聚集）结构材料在化学、光学、生物医学等领域具有广泛的应用前景,近年来引起了科学家极大的关注，近年来得到了较快的发展。本项目旨在以性能优异的、表面活性剂或聚合物修饰的疏水性纳米颗粒（无机纳米尺度大分子、纳米Au、Ag等）为基本组装单元，组装具有生物功能的多层次、多尺度的有序多孔薄膜结构；开展溶液中形成的有序聚集体的结构、性质和性能研究，结合理论计算模拟，对组装（聚集）结构从分子水平上给出理论解释，提出新的聚集理论。主要研究内容（1）纳米尺度多孔薄膜可控制备、性能研究；（2）两亲分子溶液聚集体性质、聚集体结构及结构演变和功能研究；（3）修饰石墨烯药物释放体系的构筑与生物相容性研究；（4）DNA参与多维纳米结构的构筑。实现了预期目标，全面完成了申请书中的各项内容，课题在应用基础研究上取得了较重要的突破，达到了预期目标。
成果综合统计
期刊论文
会议论文
专利
获奖
著作
期刊论文
Dimensional Architecture of Ferrocenyl-Based Oligomer Honeycomb-Patterned Films: From Monolayer to M
Gold hierarchical nanostructures formed at the solid/liquid interfaces via electroless deposition an
Assembly of foam and honeycomb films of a diblock copolymer doped with Au or Ag nanoparticles at the
Investigations into the Bending Constant and Edge Energy of Bilayers of Salt-Free Catanionic Vesicle
A Systematic Investigation and Insight into the Formation Mechanism of Bilayers of Fatty Acid/Soap M
Mechanistic Processes Underlying Biomimetic Synthesis of Silica Nanotubes from Self-Assembled Ultras
Tunable Morphology of 2D Honeycomb-Patterned Films and the Hydrophobicity of a Ferrocenyl-Based Olig
Interconvertible Self-Assembly and Rheological Properties of Planar Bilayers and Vesicle Gels in Ani
Catalytic polymer/copper composite thin films formed at the liquid/liquid interface through self-ass
One-step synthesis and assembly of one-dimensional parallel chains of CdS nanoparticles at the air–w
Fabrication of freestanding honeycomb films with through-pore structures via air/water interfacial s
Phase Behavior and Rheological Properties of Salt-Free Catanionic TTAOH/DA/H(2)O System in the Prese
Tert-butylhydroquinone recognition of molecular imprinting electrochemical sensor based on core–shel
Self-assembly and accurate preparation of Au nanoparticles in the aqueous solution of a peptide A(6)
Remarkable improvements in the stability and thermal conductivity of graphite/ethylene glycol nanofl
Self-Assembly in the Mixtures of Surfactant and Dye Molecule Controlled via Temperature and beta-Cyc
133Cs NMR and molecular dynamics simulation on bilayers of Cs+ ion binding to aggregates of fatty ac
Fabrication of composite thin films with microstructures of honeycomb, foam, and nanosphere arrays t
Nonaqueous Lyotropic Liquid-Crystalline Phases Formed by Gemini Surfactants in a Protic Ionic Liquid
Self-assembly of short peptide amphiphiles: The cooperative effect of hydrophobic interaction and hy
Efficient degradation of methyl orange via multilayer films of titanium dioxide and silicotungstic a
Synthesis and assembly of catalytically active platinum-doped polymer nanocomposites at the liquid/l
Photocatalytic degradation of methyl orange by titanium dioxide-decatungstate nanocomposite films su
Molecular Aggregates in Stable Aqueous Three-Phase Surfactant Systems and Their use in Producing CdS
Lyotropic liquid crystalline phases with a series of N-alkyl-N-methylpiperidinium bromides and water
New insights into thermal conduction mechanisms of multi-walled carbon nanotube/ionic liquid suspens
Covalent Modification of Reduced Graphene Oxide by Means of Diazonium Chemistry and Use as a Drug-De
Influence of Counterions on Micellization of Tetramethylammonium Perfluorononanoic Carboxylate in 1-
Surfactant ion-selective electrodes: A promising approach to the study of the aggregation of ionic s
Reverse lyotropic liquid crystals from europium nitrate and P123 with enhanced luminescence efficien
Wormlike micelles formed using Gemini surfactants with quaternary hydroxyethyl methylammonium headgr
Au NP Honeycomb-Patterned Films with Controllable Pore Size and Their Surface-Enhanced Raman Scatter
Molecular dynamics simulation of cetyltrimethylammonium bromide and sodium octyl sulfate mixtures: a
Loading capacity and interaction of DNA binding on catanionic vesicles with different cationic surfa
Stable ZnO/ionic liquid hybrid materials: Novel dual-responsive superhydrophobic layers to light and
Honeycomb-like thin films of Polystyrene-block-poly(2-vinylpyridine) embedded with gold or silver na
Interfacial assembly of Pt nanoparticle-doped free-standing polymer foam films and their catalytic p
Interfacial adsorption of cationic peptide amphiphiles: a combined study of in situ spectroscopic el
Periodic Mesoporous Organosilicas for Ultrahigh Selective Copper(II) Detection and The Sensing Mecha
Shear-Induced Structural Transition and Recovery in the Salt-Free Catanionic Surfactant Systems Cont
Comparison of aggregation behaviors of a phytosterol ethoxylate surfactant in protic and aprotic ion
Biphenyl-bridged periodic mesoporous organosilicas: Synthesis and in situ charge-transfer properties
Self-assembly of onion-like vesicles induced by charge and rheological properties in anionic-nonioni
Ordered patterns and structures via interfacial self-assembly: superlattices, honeycomb structures a
Fabrication of Titanium Dioxide and Tungstophosphate Nanocomposite Films and Their Photocatalytic De
Synthesis and assembly of gold nanoparticle-doped polymer solid foam films at the liquid/liquid inte
Preparation and Functions of Hybrid Membranes with Rings of Ag NPs Anchored at the Edges of Highly O
Electromotive force study on interaction between a triblock copolymer and cationic surfactants in wa
Phase transition of a quaternary ammonium gemini surfactant induced by minor structural changes of p
Highly sensitive and selective detection of Cu(II) by periodic mesoporous rhodamine derivative-based
相关项目
郝京诚的项目