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中文摘要：
研制同时具有新型检测和分离工作原理的微孔/毛细管离子色谱仪。包括检测体系中提出电势增强-电势差检测新模式，即由恒电流电解产生再生离子进行化学转化，检测恒电流下体系中被化学放大了的某两定点间的淋洗液背景电势差与样品电势差的差值，将原离子色谱化学抑制，电导检测两分立的部件改为电势增强-电势差检测的集成件，将原来复杂的交流激励电导检测电路改为简单的直流激励电势差检测电路。同时也利用表面声波技术研制离子色谱表面声波检测器，串联式表面声波传感器对溶液电导率和介电常数频率响应灵敏度高，而对温度飘逸较常规电导检测器小，提高检测的灵敏度并减小扩散，从而克服离子色谱特别是微孔/毛细管离子色谱因抑制器导制的扩散，解决微孔/毛细管离子色谱的检测。分离体系中采用新型材料和新工艺，研制高效的离子色谱固定相，结合分子识别和整体式色谱固定相技术，制备微孔/毛细管离子色谱固定相，研制具有我国自有知识产权的新型离子色谱。
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期刊论文
Reduction of the Impedance of a Contactless Conductivity Detector for Microchip Capillary Electropho
Comparison of liquid chromatographic behaviors on N-methylimidazolium functionalized ZrO2/SiO2-4 and
Preparation of dye–ligand affinity chromatographic packings based on monodisperse poly(glycidylmetha
Cation effects in the separation of calix[4]pyrroles by nonaqueous capillary electrophoresis with te
Comparison of Anion-Exchange and Hydrophobic Interactions between Two New Silica-Based Long-Chain Al
Different experimental results for the influence of immersion angle on the resonant frequency of a q
Determination of betaine, choline and trimethylamine in feed additive by ion-exchange liquid chromat
Simultaneous determination of fluoride, chloride, sulfate, phosphate, monofluorophosphate, glyceroph
Arsenic species analysis by ion chromatography–bianode electrochemical hydride generator–atomic fluo
Analysis of indandione anticoagulant rodenticides in animal liver by eluent generator reagent free i
Preparation and evaluation of a silica-based 1-alkyl-3-(propyl-3-sulfonate)
imidazolium zwitterionic
Determination of steroid sex hormones in wastewater by stir bar sorptive extraction based on poly(vi
Hydrogen-bond effect and ion-pair association in the separation of neutral calix[4]pyrroles by nonaq
Determination of impurities in flame retardant monomer 2-carboxylethyl(phenyl) phosphinic acid by io
Determination of five 4-hydroxycoumarin rodenticides in animal liver tissues by ion chromatography w
会议论文
Study of Ephedrine by Ion Chromatography and Amperometric Detection Method with a Carbon Nanotubes M
Preparation and application of porous polymer anion-exchange monolithic columns for ion chromatograp
Determination of aromatic amines in water using ionic liquid dispersive liquid - liquid microextract
Analysis of para red and sudan dyes in the chili pepper, chili oil and food additive using ionic liq
Determination of ppb level anions in sulfolane by ion chromatography with a novel column-switching i
Analysis of gentamicin sulfate injection by liquid chromatography with pulsed amperometric detection
Analysis of Etimicin Sulfate by Liquid Chromatography with Pulsed Amperometric Detection at a Platin
Determination of toluene diisocyanate in plastic playground by ion chromatography with ultraviolet d
Determination of Five 4-hydroxycoumarin Rodenticides in Whole Blood By Ion Chromatography with Fluor
Determination of Impurities in Flame Retardant Monomer (2-carboxyl ethyl(phenyl) phosphinic acid) CE
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