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中文摘要：
通过催化剂的设计，以易得原料方便地合成本课题组具有独立知识产权的双手性双钒(V)金属催化剂及其多种新型类似结构催化剂，并首次将这些催化剂用于多种结构类型底物的不对称氧化偶联反应，达到高收率高选择性的直接合成多种光活性C2轴对称联芳香化合物的目的。系统研究催化剂的结构与类型，底物的结构与类型等其他因素对催化不对称氧化偶联反应的影响，进而对催化反应的过渡态和循环机理进行研究，解决不对称氧化偶联领域目前存在的问题，推动光活性C2轴对称联芳香化合物在有机合成中的广泛应用。
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期刊论文
Amino-Indanol Catalyzed Asymmetric Michael Additions of Oxindoles to Protected 2-Amino-1-Nitroethene
Thiourea-Catalyzed Highly Diastereo- and Enantioselective Conjugate Additions of α-Substituted Cyano
Enantioselective 1,6-Michael addition of anthrone to 3-methyl-4-nitro-5-alkenyl-isoxazoles catalyzed
Highly Diastereo- and Enantioselective Michael Additions of 3-Substituted Oxindoles to Maleimides Ca
Highly Enantioselective Construction of Spiro[4H-pyran-3,3’-oxindoles] Through Domino Knoevenagel/Mi
Organocatalytic Asymmetric Michael Addition of Pyrazolin-5-ones to Nitroolefins with Bifunctional Th
An efficient synthesis of 3-(indol-3-yl)quinoxalin-2-ones with TfOH-catalyzed Friedel-Crafts type co
Catalyst-free aldol condensation of ketones and isatins under mild reaction conditions in DMF with m
Diastereo- and Enantioselective Conjugate Addition of 3-Substituted Oxindoles to Nitroolefins Cataly
A simple and eco-friendly method for the aminomethylation of 3-substituted oxindoles via three-compo
Direct Catalytic Asymmetric Aldol Reaction of 3-Substituted Oxindoles with Paraformaldehyde by Chira
Highly enantioselective aldol reaction of acetaldehyde and isatins only with 4-hydroxydiarylprolinol
Catalytic Asymmetric 1,6-Michael Addition of Arylthiols to 3-methyl-4-nitro-5-alkenyl-isoxazoles wit
Chiral Phosphoric Acid Catalyzed Diastereo- and Enantioselective 1,4-Conjugate Addition of β-Ketoest
Enantioselective Michael addition of anthrone to nitroalkenes catalyzed by bifunctional thiourea-ter
Organocatalytic Asymmetric Conjugate Addition of 3-Monosubstituted Oxindoles to (E)-1,4-Diaryl-2-but
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