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中文摘要：
口丫丙啶是有机的重要中间体，广泛用于有机合成，发展简便而有效的制备手性口丫丙啶的方法非常重要。手性口丫丙啶既可用于合成手性药物，也可用作手性配体。本项目用手性氮氮伊立德作为氮源对缺电子烯烃进和加成再环化直接得到N-非取代的手性口丫丙啶衍生物，避免了脱除N-取代基所需的强烈反应条件，是一种制备手性口丫丙啶的有效方法。
结论摘要：
英文主题词Aziridine; Aziridination; Bis-oxazoline; Asymmetric Catalysis; Olefin
成果综合统计
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期刊论文
(S)-2-Aryl-4,4-diphenyl-3,1,2-oxazaboro[3.3.0]octanes: Efficient catalysts for the asymmetric borane
Further investigation on the rearrangement mechanism in the reaction of 1,5-benzothiazepines and eth
Comparative study on mass spectrometric fragmentation of linear chiral secondary alcohols (R)-1-(4-a
Straightforward synthesis of depsiphosphonopeptides via Mannich-type multiple component condensation
Mass spectral fragmentation of 1,8-bis[4-substituted (oxazolin-2-yl)]anthracenes: ring-contraction r
Mass Spectral Fragmentation and Cyclization of (S,S)-N,N’-Bis[1-(hydroxymethyl)alkyl]anthracene/naph
Effect of temperature on the enantioselectivity in the oxazaborolidine-catalyzed asymmetric reductio
Preparation of high optically pure linear secondary alcohols via asymmetric reduction of prochiral k
Mass spectral fragmentation of (S,S)-2-substituted-4,4-diphenyl-3,1-oxazabicyclo[3.3.0]octanes: Ring
Asymmetric aziridination of chalcones catalyzed by a novel backbone 1,8-bisoxazolinylanthracene (AnB
Mass spectrometric fragmentation of 2a,4-disubstituted 2,2a,3,4-tetrahydro-2-phenoxyl-1H-azeto[2,1-d
Intermolecular phenolic hydroxy methylation occurring between chiral N,N’-bis(2-hydroxyphenyl)-2,2-d
Reaction of 2,3-dihydro-1,5-benzothiazepines and phenylacetyl chloride in the presence of triethylam
Differentiation of constitutional isomer of 2,2a,3,4-tetrahydro-4-methyl-2a-phenyl- 2-(thiophen-2-yl
Mass spectrometry of 2a,4-disubstituted 5-benzoyl-2a,3,4,5-tetrahydro-2-phenoxy-azeto[1,2-a][1,5]ben
Mass spectrometric fragmentation of 2a,4-disubstituted 2,2a,3,4-tetrahydro-2-phenyl-1H-azeto[2,1-d][
Convenient and efficient synthesis of 1,1-bis-(4-alkylthiophenyl)-1-alkenes via tandem Friedel-Craft
Rigid backbone 1,8-anthracene-linked bis-oxazolines (AnBOXes): design, synthesis, application and ch
Microwave and photoirradiation-induced Staudinger reactions of cyclic imines and ketenes generated f
Rationale on abnormal effect of temperature on the enantioselectivity in the asymmetric borane reduc
Negative ion electrospray ionization mass spectrometry of N-benzyloxycarbonyl protected 1-substitute
Chiral oxazaborolidine-catalyzed asymmetric borane reduction of alkyl 1-(4-dialkylaminophenyl) keton
Rational tuning chelate size of bis-oxazoline ligands to improve enantioselectivity in the asymmetri
A convenient and effective method for synthesizing beta-amino-alfa,beta-unsaturated esters and keton
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