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Ba2TiSi2O8晶体的质量表征及其性能研究
  • ISSN号:0258-7076
  • 期刊名称:《稀有金属》
  • 时间:0
  • 分类:O78[理学—晶体学]
  • 作者机构:[1]山东大学晶体材料研究国家重点实验室,山东济南250100, [2]潍坊学院化学化工与环境工程学院,山东潍坊261061
  • 相关基金:国家自然科学基金重点项目(51032004)和国家重点基础研究发展计划(2010CB833103)资助项目
中文摘要:

通过不断探索生长工艺及生长参数,采用提拉法成功生长了尺寸约为35mm×35mm×50mm的Ba2TiSi208晶体,所得晶体均匀透明无开裂,用绿光激光笔照射,没有明显散射颗粒。表征了晶体质量,并对其透过光谱和室温偏振拉曼光谱性能进行了研究。采用高分辨x射线衍射技术对晶体的质量进行了表征,衍射峰较窄,没有劈裂,且分布对称,说明生长的晶体晶格完整、品质较好,能够满足晶体某些光学方面的需求。用分光光度计测量了晶体的室温透过光谱,晶体[100]方向和[001]方向上的透过率接近,在340—2500nm范围内其透过率大约为84%,晶体的紫外透过截止波长为275mm,高的透过率以及短的紫外透过截止波长,表明该晶体可能在光学方面有一定应用。采用共聚焦纤维拉曼光谱仪测量了晶体在背散射X(ZZ)X,X(YY)X,Z(XY)Z和x(踞)x配置下的室温偏振拉曼光谱,并指认了某些测定的特征蜂:662cm-1属于桥对称伸缩振动vs(Si.0.Si),578,625,749,858,87613111“属于v(Ti—O)振动,858,901,930,993和1022cm-1属于p(SiO3)振动。

英文摘要:

Through exploring the growth process and parameters constantly, the Ba~TiSi2 0s single crystal, whose dimensions were a- bout 35 mm~ 35 mmx 50 mm, was successfully grown by the Czochralski method. The as-grown crystal was transparent and without cracking, no obvious scattering particles were found by a laser pen irradiation. The crystal quality was characterized, and the transmis- sion spectrum and the room temperature polarized Raman spectrum were studied. The crystal quality was characterized by high-resolu- tion X-ray diffraction(XRD), the diffraction peak with no split was relatively narrow and symmetric distribution. The results showed that the as-grown crystal had highly perfect lattice structure and good quality, which could meet the need of some optic applications. The room temperature transmission spectrum was measured by spectrophotometer, the photograph showed that the transmittance of [ 100 ] direction was similar with the transmittance of [ 001 ] direction. The transmittance in the wavelength range of 340 - 2500 nm was about 84%, and the cutoff transparency wavelength was 275 nm. The high transmittance and short cutoff transparency wavelength indicated that the crystal could be applied in optics. The room temperature polarized Raman spectrum were performed in back scatter

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期刊信息
  • 《稀有金属》
  • 中国科技核心期刊
  • 主管单位:中国科学技术协会
  • 主办单位:北京有色金属研究总院
  • 主编:屠海令
  • 地址:北京新街口外大街2号
  • 邮编:100088
  • 邮箱:xxsf@grinm.com
  • 电话:010-82241917 62014832
  • 国际标准刊号:ISSN:0258-7076
  • 国内统一刊号:ISSN:11-2111/TF
  • 邮发代号:82-167
  • 获奖情况:
  • 中文核心期刊,冶金工业类核心期刊,中国科技论文统计源期刊
  • 国内外数据库收录:
  • 俄罗斯文摘杂志,美国化学文摘(网络版),荷兰文摘与引文数据库,美国工程索引,美国剑桥科学文摘,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版),中国北大核心期刊(2000版)
  • 被引量:13688