中文摘要：

合成了四甲氧基苯基钴卟啉（CoTMPP）和四甲氧基苯基铁卟啉（FeTMPP）配合物，分别负载于经过双氧水和硝酸预处理且掺杂了MnOx的炭载体，用于质子交换膜燃料电池阴极氧还原反应电催化剂．讨论了不同中心金属离子、不同载体、不同预处理方法和不同焙烧温度对催化剂催化活性的影响．通过旋转圆盘电极技术（RDE）和紫外可见光谱（UV—vis）测试，利用循环伏安曲线（CV）和Koutevky-Levich关系式评价了电催化剂对氧还原反应的电催化性能．研究表明，CoTMPP负载于双氧水处理过的炭载体BP2000上活性最好，焙烧的最佳温度是900℃，同时发现在载体中掺杂MnOx并没有达到预期效果．

英文摘要：

To obtain cathode electrocatalysts for the oxygen reduction in proton exchange membrane （PEM） fuel cell, iron and cobalt tetramethoxyphenylporphyrins adsorbed on pretreated carbons, including black pearls 2000 （BP） and Vulcan XC-72 （Vulcan） respectively by depositing MnOx were investigated in detail The effects of different central metal ions, carbon supports, pretreatment methods and various heat-treatment temperatures were compared. The catalysts were evaluated by RDE in 0.5 mol·L^-1 H2SO4. The best results were obtained for CoTMPP on BP pretreated by H2O2. The most active and stable catalysts were obtained by calcining at a high temperature （900℃）. After heat treatment at 900℃, Co N4 bond structure in CoTMPP catalyst was no longer detected which meant that the central structure of the catalyst was changed during heat-treatment. Trying to deposit MnOx in carbons did not achieve the expected result in acid medium.