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中文摘要：
采用铂微电极观察到了室温下（25±1）℃甲苯单一溶剂中C60和C70的六步单电子电化学还原过程．在甲苯中采用一般的有机相支持电解质溶饵度差，电势窗口也不宽．实验结果表明，离子液体[Tetrahexylammonium bis（trifluoromethylsulfonyl）imide，THA—Tf2N]在甲苯中具有良好的溶解度，因而可以作为这种非极性溶剂的理想支持电解质，并且该体系可以提供宽达-3．7V（相对于二茂铁电对，Fe^＋／Fe）的电化学还原窗口，这是在室温下实现C60^6-和C70^6-的电化学检测的主要原因．
英文摘要：
The complete set of six one-electron reductions of C60 and C70 was observed for the first time in a single organic solvent, toluene, at room temperatures （25 ± 1 ） ℃ by cyclic voltammetry and differential pulse voltammetry on a Pt disk uhramicroelectrode （UME）. A type of room-temperature ionic liquid （ RTIL）, tetrahexylammonium bis（trifluoromethylsulfonyl）imide（ THA-Tf2N）, was found to have an excellent solubility in toluene, and was employed as the supporting electrolyte to increase the conductivity of toluene. This electrochemical system presents a wide potential window down to - 3.7 V vs. ferrocenium/ferrocene （ Fe^ ＋/Fe）, which essentially allows electrochemical detection of C60^6- and C70^6- at room temperature. We also discussed the reasons why does this RTIL dissolve well in toluene, and the future applications of such system.
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