利用金属有机物化学气相沉积技术在蓝宝石衬底上低温生长GaN: Mg薄膜,对不同源流量的GaN:Mg材料特性进行优化研究.研究表明二茂镁(CP2Mg) 和三甲基镓(TMGa)物质的量比([CP2Mg]/[TMGa])在1.4×10^-3—2.5×10^-3范围内,随[CP2Mg]/[TMGa]增加,晶体质量提高,空穴浓度线性增加.当[CP2Mg]/[TMGa]为2.5×10^-3时获得空穴浓度与在较高温度生长获得的空穴浓度相当,且薄膜表面较粗糙.采用 [CP2Mg]/[TMGa]为2.5×10^-3的p型GaN层制备的发光二极管,在注入电流为20 mA时,输出光强提高了17.2%.
GaN: Mg films have been grown on sapphire at low temperature by metal-organic chemical vapor deposition, the properties of different source flux GaN: Mg materials were studied. When the molar ratio of CP2Mg and TMGa is between 1.4×10^-3 and 2.5×10^-3, the quality of crystal was improved with the increasing molar ration, and the hole concentration was increased linearly. When the molar ratio is 2.5×10^-3,the concentration is equal to that of the film grown at higher temperature, and the surface morphology is more coarser. Taking the p-GaN layer with molar ratio of CP2Mg and TMGa of 2.5×10^-3 as the light-emitting diode, when the inject current is 20 mA, the output light power was increased by 17.2%.