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轻质油藏注空气过程中原油低温氧化反应的O2-CO2转换率
  • ISSN号:1671-1815
  • 期刊名称:《科学技术与工程》
  • 时间:0
  • 分类:TE357[石油与天然气工程—油气田开发工程]
  • 作者机构:[1]中国石油大学(华东)石油工程学院,青岛266580, [2]中石油煤层气有限责任公司韩城分公司,韩城715400
  • 相关基金:长江学者和创新团队发展计划(IRT1294)资助
中文摘要:

根据注空气过程中原油低温氧化反应机理和实验结果,分析氧气消耗率和CO2转换率及其影响因素.根据不同条件下原油低温氧化实验和高温氧化实验,计算分析了不同反应条件下的CO2转换率.实验结果表明,原油的低温氧化活性和CO2转化率主要受原油种类、反应温度、气体压力和砂的影响.温度和压力越高,反应速率越快,氧气消耗越完全,CO2转换率越大;加入砂后,反应速率加快,氧气消耗量增多,CO2转换率增高.与高温氧化相比,低温氧化的CO2转换率低于65%,通常在20%-50%范围内.

英文摘要:

Air injection into light oil reservoirs is an effective technique for improving oil recovery, and thistechnique mainly depends on a spontaneous low temperature oxidation (LTO) process which occurs at reservoirtemperature. During LTO process of air injection, oxygen in the injected air is consumed and carbon dioxide can beproduced in the reservoir, leading to flue gas flooding and generating a significant amount of heat. Products of theair-oil oxidation reaction mainly include oxidized hydrocarbons and carbon oxides. Oxygen consumption rate andCO2 conversion ratio are analyzed based on the mechanisms of the LTO reaction and experimental results. The COgconversion ratios at different reaction conditions were calculated and the corresponding influencing factors are ana-lyzed. Experimental results show that the LTO activity of crude oils and the CO conversion ratio is mainly affectedby oil composition, and reaction temperature. Higher temperatures and pressures and existence of reservoir sandscan promote faster reaction rate, more or complete oxygen consumption, as well as higher CO2 conversion ratio. TheCO2 conversion ratio can be used to determine which reaction (low temperature or high temperature reactions) isprevailed at reservoir conditions.

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期刊信息
  • 《科学技术与工程》
  • 北大核心期刊(2011版)
  • 主管单位:中国科学技术协会
  • 主办单位:中国技术经济学会
  • 主编:明廷华
  • 地址:北京市学院南路86号
  • 邮编:100081
  • 邮箱:ste@periodicals.net.cn
  • 电话:010-62118920
  • 国际标准刊号:ISSN:1671-1815
  • 国内统一刊号:ISSN:11-4688/T
  • 邮发代号:2-734
  • 获奖情况:
  • 国内外数据库收录:
  • 中国中国科技核心期刊,中国北大核心期刊(2011版),中国北大核心期刊(2014版)
  • 被引量:29478