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电厂湿法脱硫系统对烟气中细颗粒物脱除作用的实验研究
  • ISSN号:0258-8013
  • 期刊名称:《中国电机工程学报》
  • 时间:0
  • 分类:TK16[动力工程及工程热物理—热能工程]
  • 作者机构:[1]清华大学热科学与动力工程教育部重点实验室,北京市海淀区100084
  • 相关基金:国家重点基础研究发展规划基金项目(2002CB211600);国家科技攻关项目(2004BA401A12-4).
中文摘要:

采用Andersen 8级撞击器对某300MW燃煤电厂湿法烟气脱硫(wet flue gas desulphurization,WFGD)系统前后的飞灰颗粒物进行采集,获得了烟气中飞灰颗粒物的质量浓度和粒径分布特性。采样工况分别为100%和70%锅炉负荷。使用场发射扫描电镜-能谱分析,X射线荧光分析和电感耦合等离子体-原子发射光谱分析法对颗粒物进行了形貌分析和主、次量元素含量的检测。结果表明,WFGD系统入口飞灰质量粒径呈典型的双峰分布,峰值分别在1和3μm处,颗粒多呈规则球形,PM2.5与PM10质量比为0.434,飞灰总浓度约为85mg/m^3标准状态;出口处飞灰质量粒径分布也呈现双峰性,其中细颗粒比例增大,PM2.5与PM10质量比为0.764,细颗粒间相互聚集粘连形成不规则的块状结构,飞灰总浓度在23mg/m^3(标准状态)以下,总飞灰的脱除效率为74.5%,分级脱除效率随粒径减小而明显下降。经过WFGD系统后,细颗粒上S和Ca元素含量增大,而Al,Ba,Fe,Mn和Si元素的含量降低。计算表明,WFGD出口烟气中新增的石灰石与石膏颗粒分别占颗粒物质量的47.5%和7.9%。

英文摘要:

Fly-ash particles from the inlet and outlet of the wet flue gas desulphurization(WFGD) system in a 300 MW coal-fired power plant were sampled by an Andersen 8-stage impactor and the mass concentrations and size distributions of fly-ash particles in flue gas were obtained. The samplings were developed under 100% and 70% boiler loads. The microstructure, major and minor-element concentrations of particles were measured using field emission scanning electron microscopy/energy dispersive X-ray spectrometry(FESEM- EDS), X-ray fluorescence(XRF) and inductively coupled plasma - atomic emission spectrometry (ICP-AES), respectively The results indicate that the mass size distribution of fly-ash particles in the inlet of the WFGD system is typically disturbed bimodally, the peaks are approximate at 1 and 3 μm. And the shape of particles is regular sphericity, the mass ratio of PM2.5 to PM10 is about 0.434. The total mass concentration is about 85 mg/m^3. In the outlet of the WFGD system, the mass size distribution of fly-ash particles is also bimodal. The proportion of fine particles increased, the mass ratio of PM2.5 to PM10 is about 0.764, Some fine particles are conglutinated and formed irregular agglomerate. The total mass concentration is under 23 mg/m^3, the removal efficiency of total particles is 74.5%. The size removal efficiency is decreased observably with the range of particle size decreasing. After the WFGD system, the element concentrations of S and Ca in fine particles are augmented, and the concentrations of Al, Ba, Fe, Mn and Si are decreased oppositely. Fine particles in the outlet of WFGD system consist of about 47.5% limestone and 7.9% gypsum particulate matters.

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期刊信息
  • 《中国电机工程学报》
  • 北大核心期刊(2011版)
  • 主管单位:中国科学技术协会
  • 主办单位:中国电机工程学会
  • 主编:张文涛
  • 地址:北京清河小营东路15号 中国电力科学研究院内
  • 邮编:100192
  • 邮箱:pcsee@epri.sgcc.com.cn
  • 电话:010-82812536 82812534 82812545
  • 国际标准刊号:ISSN:0258-8013
  • 国内统一刊号:ISSN:11-2107/TM
  • 邮发代号:82-327
  • 获奖情况:
  • 1992年全国优秀科技期刊三等奖,1992年中国科协优秀科技期刊二等奖,1996年中国科协优秀科技期刊二等奖,中国期刊方阵“双效”期刊
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  • 俄罗斯文摘杂志,波兰哥白尼索引,德国数学文摘,荷兰文摘与引文数据库,美国工程索引,美国剑桥科学文摘,英国科学文摘数据库,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版),中国北大核心期刊(2000版)
  • 被引量:98970