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Cu2ZnSnS4薄膜太阳能电池材料的研究现状
  • ISSN号:1005-023X
  • 期刊名称:《材料导报》
  • 时间:0
  • 分类:O614[理学—无机化学;理学—化学] TQ134.32[化学工程—无机化工]
  • 作者机构:[1]College of Chemistry and Materials Engineering, Wenzhou University, Wenzhou 325035. China, [2]College of Materials Science and Engineering, Tongji University, shanghai 201804, china, [3]College of Light Industry, Liaoning University, Shenyang 110036, China
  • 相关基金:The authors gratefully acknowledge the financial support from the National Natural Science Foundation of China (Grant Nos. 50972107 and 51272059), the Key Scientific and Technological Innovation Teams of Zhejiang Province, China (No. 2009R50010), the Natural Science Foundation of Liaoning Province, China (No. 201202087) and Program of Science and Technology Project of Wenzhou, China (No. G20110012).
中文摘要:

<正>Flower-like Cu2SnS3 nanostructures composed of nano-flakes were successfully synthesized by solvothermal technique at 180℃for 16 h.In the preparation process,CuCI2·2H2O,SnCl2·2H2O and thiourea were used as raw materials,and ethylene glycol were used as solvent.The results showed that the obtained product was pure phase Cu2SnS3.The average diameter of Cu2SnS3 flowers and the thickness of the nano-flakes were about 1—1.5μm and 10 nm,respectively.The influence of reaction time and solvents on the morphology,size and structure of the products was investigated by powder X-ray diffraction and fieldemission scan electron microscopy(FESEM).The ultraviolet-visible absorption spectrum measurement indicated that the band gap of the sample was about 1.26 eV and could be applied to the absorbing layer of thin solar cell.The possible formation mechanism of flower-like Cu2SnS3 was also proposed and discussed.更多还原

英文摘要:

Flower-like Cu2SnS3 nanostructures composed of nano-flakes were successfully synthesized by solvothermal technique at 180 ℃ for 16 h. In the preparation process, CuCl2·H2O, SnCl2·2H2O and thiourea were used as raw materials, and ethylene glycol were used as solvent. The results showed that the obtained product was pure phase Cu2SnS3. The average diameter of Cu2SnS3 flowers and the thickness of the nano-flakes were about 1-1.5 μm and 10 nm, respectively. The influence of reaction time and solvents on the morphology, size and structure of the products was investigated by powder X-ray diffraction and field-emission scan electron microscopy (FESEM). The ultraviolet-visible absorption spectrum measurement indicated that the band gap of the sample was about 1.26 eV and could be applied to the absorbing layer of thin solar cell. The possible formation mechanism of flower-like Cu2SnS3 was also proposed and discussed.

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期刊信息
  • 《材料导报:纳米与新材料专辑》
  • 主管单位:重庆西南信息有限公司(原科技部西南信息中心)
  • 主办单位:重庆西南信息有限公司(原科技部西南信息中心)
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  • 地址:重庆市渝北区洪湖西路18号
  • 邮编:401121
  • 邮箱:matreved@163.com
  • 电话:023-67398525
  • 国际标准刊号:ISSN:1005-023X
  • 国内统一刊号:ISSN:50-1078/TB
  • 邮发代号:
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  • 被引量:3397