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A novel strong green phosphor: K3Gd(PO4)2:Ce^3+, Tb^3+ for a UV-excited white light-emitting-diode
  • ISSN号:1674-1056
  • 期刊名称:《中国物理B:英文版》
  • 时间:0
  • 分类:TN312.8[电子电信—物理电子学] TQ132.41[化学工程—无机化工]
  • 作者机构:[1]College of Materials Science and Engineering, Kunming University of Science and Technology, Kunming 650093, China, [2]Key Laboratory of Advanced Materials of Yunnan Province, Kunming 650093, China
  • 相关基金:Project supported by the National Natural Science Foundation of China (Grant Nos. 11204113, 61265004, and 51272097), the Foundation of Application Research of Yunnan Province, China (Grant No. 2011FB022), the Chinese Specialized Research Fund for the Doctoral Program of Higher Education (Grant No. 20115314120001), the Postdoctoral Science Foundation of China (Grant No. 2011M501424), and the National Basic Research Program of China (Grant No. 2011CB211708).
中文摘要:

A series of K3Gd1 x y(PO4)2:xCe3+,yTb3+phosphors are synthesized by the solid-sate reaction method.X-ray diffraction and photoluminescence spectra are utilized to characterize the structures and luminescence properties of the as-synthesized phosphors.Co-doping of Ce3+enhances the emission intensity of Tb3+greatly through an efficient energy transfer process from Ce3+to Tb3+.The energy transfer is confirmed by photoluminescence spectra and decay time curves analysis.The efficiency and mechanism of energy transfer are investigated carefully.Moreover,due to the nonconcentration quenching property of K3Tb(PO4)2,the photoluminescence spectra of K3Tb1 x(PO4)2:xCe3+are studied and the results show that when x=0.11 the strongest Tb3+green emission can be realized.

英文摘要:

A series of K3Gd1-x-y(PO4)2:xCe^3+, yTb^3+ phosphors are synthesized by the solid-sate reaction method. X-ray diffraction and photoluminescence spectra are utilized to characterize the structures and luminescence properties of the as-synthesized phosphors. Co-doping of Ce^3+ enhances the emission intensity of Tb^3+ greatly through an efficient energy transfer process from Ce^3+ to Tb^3+. The energy transfer is confirmed by photoluminescence spectra and decay time curves analysis. The efficiency and mechanism of energy transfer are investigated carefully. Moreover, due to the non- concentration quenching property of K3Tb(PO4)2, the photoluminescence spectra of K3Tb1-x(PO4)2:xCe^3+ are studied and the results show that when x = 0.11 the strongest Tb^3+ green emission can be realized.

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期刊信息
  • 《中国物理B:英文版》
  • 中国科技核心期刊
  • 主管单位:中国科学院
  • 主办单位:中国物理学会和中国科学院物理研究所
  • 主编:欧阳钟灿
  • 地址:北京 中关村 中国科学院物理研究所内
  • 邮编:100080
  • 邮箱:
  • 电话:010-82649026 82649519
  • 国际标准刊号:ISSN:1674-1056
  • 国内统一刊号:ISSN:11-5639/O4
  • 邮发代号:
  • 获奖情况:
  • 国内外数据库收录:
  • 被引量:406