欢迎您！东篱公司
退出
-
申报数据库
-
立项数据库
-
成果数据库
-
项目获奖数据库
中文摘要：
以五乙酰基葡萄糖和甲基丙烯酸-2-羟基乙酯（HEMA）为原料，以路易斯酸-三氟化硼乙醚络合物（BF3·Et2O）为催化剂，方便地合成了一种含糖单体-甲基丙烯酸-2-（2′，3′，4′，6′-四-O-乙酰基-β-D-吡喃葡萄糖氧）乙酯（AcGEMA）．该单体与丙烯腈（AN）经自由基溶液聚合的方法进行了共聚．单体和共聚物结构分别经红外、核磁证实．以水接触角测定脱乙酰保护后的含糖共聚物膜表面，结果表明脱乙酰化可显著提高膜表面亲水性．因此，用共聚法对聚丙烯腈膜改性，使其表面引入糖基，可以改善聚合物膜的亲水性；同时糖基的引入为其在生物材料领域的应用开辟了新的途径．
英文摘要：
A carbohydrate containing monomer, 2-（2′,3′,4′,6′-tetra O-acetyl-β-D-glucosyloxy） ethyl methacrylate （AcGEMA）, was synthesized conveniently by the reaction of peracetylated glucose and 2-hydroxyethyl methacrylate （HEMA） catalyzed with boron trifluoride-diethyl ether complex （BF3 · Et2O）. The monomer was copolymerized with acrylonitrile （AN） by free radical polymerization in solutions. FT IR and ^1 H NMR spectroscopies were used to characterize the synthesized monomer and copolymers. Upon removal of the acetyl groups from the copolymer film, water contact angles of the film surface decreased remarkably, which indicated a more hydrophilic surface was obtained. The addition of carbohydrate moiety to AN-based copolymer increases its hydrophilicity and allows for potential application in biomaterial area.
同期刊论文项目
同项目期刊论文
Polyacrylonitrile-Based Nanofibrous Membrane with Glycosylated Surface for Lectin Affinity Adsorptio
Effect of Chitosan Modification on the Behavior of the Immobilized Redox Enzyme on Nanofibrous Membr
Thermo-responsive stick-slip behavior of advancing water contact angle on the surfaces of poly(N-iso
Surface hydrophilisation and antibacterial functionalisation for microporous polypropylene membranes
Colorimetric and fluorescent sensor constructing from the nanofibrous membrane of porphyrinated poly
Nanofibrous sugar sticks electrospun from glycopolymers for protein separation via molecular recogni
Enhancing the hydrophilicity of polypropylene microporous membranes by the grafting of 2-hydroxyethy
Fabrication of glycosylated surface on polymer membrane by UV-induced graft polymerization for lecti
Novel photoinduced grafting-chemical reaction sequence for the construction of a glycosylation surfa
Immobilization of catalase on electrospun nanofibrous membranes modified with bovine serum albumin o
Surface hydrophilization of microporous polypropylene membrane by the interfacial crosslinking of po
Recognition Mechanism of Theophylline-Imprinted Polymers: Two-Dimensional Infrared Analysis and Dens
Surface modification of nanofibrous poly(acrylonitrile-co-acrylic acid) membrane with biomacromolecu
Polymer surfaces structured with random or aligned electrospun nanofibers to promote the adhesion of
Construction of comb-like poly(N-isopropylacrylamide) layers on microporous polypropylene membrane b
Carbon Nanotube-Filled Nanofibrous Membranes Electrospun from Poly(acrylonitrile-co-acrylic acid) fo
Linear and Comb-Like Acrylonitrile/N-Isopropylacrylamide Copolymers Synthesized by the Combination o
Preparation and characterization of magnetic nanofibrous composite membranes with catalytic activity
Honeycomb-patterned films of polystyrene/poly(ethylene glycol): preparation, surface aggregation and
Covalent immobilization of lipase from Candida rugosa onto poly(acrylonitrile-co-2-hydroxyethyl meth
Immobilization and properties of lipase from Candida rugosa on electrospun nanofibrous membranes wit
Surface glycosylation of polyacrylonitrile ultrafiltration membrane to improve its anti-fouling perf
Chitosan-Modified Poly(acrylonitrile-co-acrylic acid) Nanofibrous Membranes for the Immobilization o
A facile approach for the surface modification of poly(vinylidene fluoride) membrane via surface-ini
Catalase immobilization on electrospun nanoribers: Effects of porphyrin pendants and carbon nanotube
Adsorption and activity of lipase from Candida rugosa on the chitosan-modified poly(acrylonitrile-co
Cytocompatibility of poly(acrylonitrile-co-N-vinyl-2-pyrrolidone) membranes with human endothelial c
Construction of glycosylated surfaces fox poly(propylene) beads with a photoinduced grafting/chemica
Surface engineerings of polyacrylonitrile-based asymmetric membranes towards biomedical applications
位置：