研究了南海红树林内源真菌Fusariumsp.#ZZF51富集铀(Ⅵ)的特性。初步结果表明,受试菌吸附铀(Ⅵ)的吸附平衡时间为60rain,常温常压下吸附最佳条件为pH-4.0,铀(Ⅵ)的初始质量浓度为50mg/L,吸附时间为60rain,铀(Ⅵ)的吸附容量为15.46mg/g。Langmuir和Freundlich方程均能较好地描述该受试菌对铀(Ⅵ)的平衡吸附行为。此外,通过真菌Fusariumsp.#ZZF51吸附铀(Ⅵ)前后红外光谱图可知,在吸附过程中,羟基和羰基都起重要作用。
The uranium(Ⅵ) biosorption was studied in detail by using the biomass of man- grove endophytic fungus Fusarium sp. # ZZF51 from the South China Sea. The results show that the uranium (Ⅵ) biosorption process onto the tested fungus powders is optimized at pH=4.0, adsorption time 60 rain, and uranium(Ⅵ) initial mass concentration 50 mg/L with 15.46 mg/g of adsorption capacity. The experimental data are analyzed by using the Lang- muir model and the Freundlich model, and they provide better correlation with the experi- mental data for adsorption of uranium (Ⅵ). In addition, according to Fourier transforminfrared spectra for Fusariurn sp. # ZZF51 before and after loaded wlttl uramum( Ⅵ), alillllU and hydroxyl groups range from 3 408 cm^-1 to 3 452 cm^-1 , and the stretching vibrations of carbonyl band shifts from 1 649 cm^-1 to1 631 cm^-1. By comparing with Fourier transform infrared spectra for the tested fungus before and after loaded with uranium( VI), hydroxyl and carbonyl groups have an important contribution to the adsorption process.