摘要:采用铜模吸铸法制备Cu50Zr42Al8非晶合金,并对其进行高温快速处理,通过X射线衍射(XRD)、差示扫描量热法(DSC)、场发射扫描电镜(SEM)、微机控制电子式万能力学试验机研究高温处理对Cu基非晶合金结构和压缩性能的影响。结果表明,873K处理后的试样未析出晶体相,其它试样析出相均含有Cu10Zr7和A1Cu2Zr,熔点以上处理后的试样还析出了CuZr2,且随着处理温度的升高析出相的体积分数逐渐增大;铸态试样塑性和强度最好,且随着处理温度的升高断裂强度先减小后增大,1148K处理的试样断裂强度最低,1223K处理的试样断裂强度是处理后试样中最高的,且经1198K处理的试样是处理后的试样中唯一出现塑性的,塑性应变为0.83%。
Cu50Zr42Al8 amorphous alloy was prepared by copper mold casting process, then high temperature treatment at different temperatures was carried out. Structural, thermal and compressive properties of the an- nealed BMGs were studied by X-ray diffraction (XRD), differential scanning calorimetry (DSC), scanning elec- tron microscope (SEM) and compressive test methods. The results indicated: the sample treated at 873 K didn' t form new phase, the other samples formed CU10 Zr7 and AlCu2Zr new phases, and with the treatment tempera- ture increasing, the volume fraction of precipitated phase increased; the strength and plasticity of as-cast speci- men was the best, and with the heat treatment temperature increasing, fracture strength firstly increased and then decreased. The sample treated at 1 148 K had the lowest fracture strength, the 1 123 K had the highest in the samples treated. In addition to the as-cast specimen, only the sample treated at 1 198 K showed plasticity with the plastic strain 0.83 %.