采用溶胶-凝胶法在石英玻璃上制备掺锡氧化锌(ZnO:Sn)透明导电薄膜,研究了干燥温度和退火温度对薄膜结晶度、微观结构、光电特性的影响。采用X射线衍射仪(CRD)、扫描电子显微镜(SEM)、紫外一可见光光度计(UV—VIS)和四探针法等分析方法对ZnO:Sn薄膜进行分析表征,结果表明:在300℃温度下干燥10min后,在700℃空气中退火1h制备出的ZnO:Sn薄膜表面平整,具有c轴择优取向,平均透过率达到92%以上,电阻率仅为113.6n-cm。关键词透明氧化物半导体;ZnO薄膜;Sn掺杂;溶胶一凝胶法
Sn-doped ZnO (ZnO:Sn) thin films were prepared on silica glass substrates by the sol-gel method. The effects of different drying temperatures and annealing temperatures on the crystallinity, structural, optical and electrical properties of the films were investigated. The ZnO:Sn thin films were characterized by X-ray diffraction (XRD), scanning electron microscope (SEM), Ultra Violet-visible spectra (UV-VIS) and four-point probe method. The results show that ZnO : Sn thin films prepared by drying at 300 ℃ for 10 minutes, then annealed in the air at 700 ℃ for 1 hour have the smoother surface, the high-preferential c-axis orientation, the average transmittance of 92 % and the resistivity of 13.6 Q.cm.