研究了十溴联苯醚(BDE-209)共存条件下嗜麦芽窄食单胞菌对水中zn2+的吸附特性,并通过对菌体进行失活处理、红外光谱和X.光电子能谱分析,探讨了吸附机理。结果表明,zn2+的吸附符合Freundlich吸附模式;嗜麦芽窄食单胞菌对zn2+吸附作用明显,2.5g/L菌体在2h时,对初始浓度为2.0nlg/LZn2+的去除率达92%。BDE-209对菌体吸附zn2+有一定的抑制作用。各因素对嗜麦芽窄食单胞菌吸附zn2+的影响程度由大到小依次为:投菌量〉pH〉BDE-209浓度。菌体对zn2+的吸附除表面吸附外,还存在跨细胞壁细胞膜的主动运输和积累等作用。菌体中的酰胺基与羟基均参与了zn2+吸附,而且菌体表面ca2+与zn2+发生了离子交换,吸附后zn2+的价态不变。
The characteristics of Zn2+ biosorption by Stenotrophomonas maltophilia in the presence of decabromodiphenyl ether (BDE-209) were studied and its mechanisms were explored through cell inactivation, fourier transform infrared spectroscopy observation and X-ray photoelectron spectroscopy analysis. Freundlich adsorption isotherms fitted well to describe Zn2+ biosorption behavior. S. maltophilia was an effective strain to remove more than 90% of Zn2+ after dealing with 2.0 mg/L Zn2+ solution for 2 h with 2.5 g/L biomass. However, BDE-209 had an inhibitory effect on Zn2+ biosorption. The sequence of factors influencing Zn2~ biosorption was biomass 〉 pH 〉 concentration of BDE-209. Zn2 + biosorption by S. maltophilia included surface adsorption, transmembrane active transport and bioaccumulation. The mechanism study clarified acetyl amino group and hydroxyl group binded Zn2+ , Ca2. on the cell wall exchanged with Zn2+. Moreover, the valence state of Zn2+ was not changed by biosorption.