研究鼠李糖脂对苏云金芽孢杆菌J-1降解/吸附水体中BDE-209/Pb的影响及机理。研究结果表明:一定质量浓度范围的鼠李糖脂(20-100 mg/L)能促进BDE-209/Pb复合污染体系中菌J-1对BDE-209的降解和对Pb的吸附;50 mg/L的鼠李糖脂可将菌J-1对BDE-209(1mg/L)的降解率提高38.37%,对Pb(1 mg/L)的吸附率提高16.46%;鼠李糖脂能以单分子或胶束形式与Pb结合,从而缓解菌J-1在降解BDE-209的过程中Pb对菌体的毒性,促进BDE-209的生物降解。高浓度鼠李糖脂对菌J-1降解BDE-209和吸附Pb有抑制作用;当鼠李糖脂质量浓度大于200 mg/L时会造成菌体萎缩死亡。
The effect and mechanism of rhamnolipid on Bacillus thuringiensis J-1 degrading/adsorbing BDE-209/Pb in water body were studied. The results show that rhanmolipid of certain mass concentration range (20-100 mg/L) can enhance the degradation of BDE-209 and the adsorption of Pb by J-1 in BDE-209/Pb combined pollution system. The degradation efficiency of BDE-209 (1 mg/L) and the adsorption capability of Pb (1 mg/L) increase by 38.37% and 16.46%, respectively, when the concentration of rhamnolipid is 50 mg/L. Rhamnolipid combines with Pb in the form of single molecule or micelle, alleviating the toxicity of Pb to J-1 and enhancing BDE-209 biodegradation. High concentration of rhamnolipid can inhibit J-1 's ability to degrade BDE-209 and adsorb Pb. The high level rhamnolipid (〉 200 mg/L) can cause J-1 to shrivel and die.