研究在含铬型钒钛矿烧结过程中MgO对烧结矿转鼓强度(TI)及低温还原粉化指数(RDI)的影响,采用熔点熔速仪和SEM-EDS研究MgO对含铬型钒钛矿熔化特性的影响,并探讨MgO在烧结过程的迁移行为。结果表明:当MgO含量为1.95%-2.63%(质量分数)时,MgO含量的提高对含铬型钒钛矿熔化特性未产生不利影响;当MgO含量由1.95%增加到2.63%时,烧结矿转鼓强度由50.33%提高到53.40%,RDI+3.15由80.57%上升到82.71%;MgO的迁移主要以Mg2+的形式通过类质同象形式取代Fe^2+而形成含镁磁铁矿(Fe,Mg)O·Fe2O3,Mg^2+的含量随着MgO含量的提高而增多,其迁移历程为:Fe O·Fe2O3→(Fe,Mg)O·Fe2O3→(Mg,Fe)O·Fe2O3→MgO·Fe2O3。
The influences of MgO on the tumbler index (TI), reduction degradation index (RDI) and melting characteristics of V-Ti-Cr magnetite sinter were studied. The transference and interaction mechanism of MgO in sintering of V-Ti-Cr magnetite were investigated by melting point-rate measuring and SEM-EDS. The results show that, when MgO content (mass fraction) increases from 1.95%to 2.63%,the melting characteristic of V-Ti-Cr magnetite does not become worse. Furthermore, TI increases from 50.33%to 53.40%and RDI+3.15 increases from 80.57%to 82.71%with increasing MgO content from 1.95%to 2.63%. The transference of MgO is mainly in the form of Mg^2+, which diffuses into crystal lattice of magnetite and forms (Fe, Mg)O·Fe2O3,and the content of Mg^2+ in magnetite increases with increasing MgO content. The course of transference of MgO is FeO→Fe 2 O 3→(Fe, Mg)O→Fe 2 O 3→(Mg, Fe)O→Fe 2 O 3→MgO→Fe2O3.