合成了8-氨基喹啉Schiff碱乙酸锰配合物,并解析了单晶结构。晶体属单斜晶系,空间点群为P2(1)/n。晶胞参数:a=8.3797(10)A,b=20.941o(3)h,c=11.178l(2)A,8—104.2860(10)。,V=1900.87(5)A3,Z=4。
A trinuclear complex, consisting of manganese(Ⅱ) ions and diprotonated N-(8-quinolyl)5alicylaldimine ligands, has been synthesized and characterized structurally. Its crystal belongs to monocllnic system, space group P2(1)/n with cell parameters a = 8. 3797(10) A, b = 20. 9410(3)A, c = 11. 1781(2)A, ( = 104. 2860(10)^o, V = 1900.87(5) A3, Z= 4.