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中文摘要：
以CdCl2和1，3-二（N-咪唑基甲基）苯（mbix）为原料，用挥发法合成了新型二维镉配位聚合物——[Cd（mbix）2Cl2]n（1），其结构经IR，XRD和元素分析表征。1属三斜晶系，空间群P-1，晶胞参数a=7．8784（18）A，b=8．856（2）A，c=11．088（3）A，α=106．662（3），β=91．046（3）°，γ=107．393（3）°，V=702．7（3）A^3，Z=1，Dc=1．559g·cm^-3，μ=1．001mm^-1，F（000）=334，R1=0．0239，μR2=0．0525。1中cd（Ⅱ）与四个mbix配体的四个氮原子及两个氯原子配位，形成一个畸变八面体构型。Cd（Ⅱ）与两个mbix配体桥联形成一维链，链与链之间又通过竹一盯相互作用形成二维层状结构。
英文摘要：
A novel two dimensional Cd （ Ⅱ ） complex, [ Cd （mbix） 2 Cl2 ] n （ 1 ）, was synthesized by volatile method from cadmium chloride and 1,3-bis（imidazol-1-ylmethyl） benzene（mbix）. The structure was characterized by IR, XRD and elemental analysis. 1 belongs to tficlinic, space group P-1 with a = 7. 878 4（18） A, b=8.856（2） A, c=11.088（3） A, a=106.662（3）°, fl= 91.046（3）°, γ=107.393（3）°, V=702.7（3） A^3, Z=1, Dc=1.559 g · cm^-3, μ=1.001 -1 F（000） 334 R1 =0.023 9 ,ωR2 =0.052 5. The Cd atom is six-coordinated with slightly , distorted octahedral coordination geometry by four N atoms from four mbix ligands and two Cl atoms. The Cd （ Ⅱ ） is bridged by two mbix ligands into a one-dimensional chain, which is further linked into network by π -π interaction.
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