基于配位作用以及配体之间的多种弱相互作用(如氢键、π-π堆垛作用等),金属离子与有机配体之间经自组装形成结构新颖、性能独特的金属—有机超分子配合物,本文主要介绍了配位化学和金属—有机超分子框架结构的基本原理及其研究方法。
In recent years,based on coordinative interactions and diversified supramolecular interactions(such as hydrogen bonding and π-π stacking,etc.),the formation of metal-organic supermolecular compounds with novel structures and properties by self-assembling between metal ions and organic ligand have been the most intensive research topic in crystal engineering of metal complexes,coordination chemistry and supermolecular chemistry.The research of metal-organic supramolecular frameworks is one of the hot topic in supramolecular interactions.Here,the concepts and principles of coordination chemistry,supramolecular chemistry and metal-organic frameworks(MOFs) are simply introduced.