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中文摘要：
以4,4＇-磺酰基二苯甲酸（H2SDBA）和4,4＇-二[（1H-咪唑基）甲基]联苯（bimb）为配体,采用水热合成法合成了一种新型的二维镍（Ⅱ）配位聚合物[Ni（SDBA）（bimb）（H2O）2]n（1）,其结构经X-射线单晶衍射和元素分析表征。1属单斜晶系,空间群C2/c,晶胞参数a=34.448（11）,b=5.563 2（17）,c=18.509（6）,β=118.830（8）°,V=3 107.4（17）3,Z=4,Dc=1.525 g.cm-3,μ=0.753 mm-1,F（000）=1 480,R1=0.040 8,wR2=0.111 2。1中Ni（Ⅱ）与两个bimb的两个氮原子,两个SDBA2-的两个氧原子和两个水分子的两个氧原子配位,形成一个畸变的八面体几何构型。Ni（Ⅱ）经SDBA2-桥联形成一维波浪状链,链与链之间又通过bimb配体形成二维格子层状结构。
英文摘要：
A novel two dimensional Ni（Ⅱ） complex,[Ni（SDBA）（bimb）（H2O）2]n（1）,was synthesize by solvothermal reactions of 4,4′-sulfonyldibenzoic acid（H2SDBA） and 4,4′-bis[（1H-imidazol-1-yl）methyl]-biphenyl（bimb）.The structure was characterized by X-ray single crystal diffraction and elemental analysis.1 belongs to monoclinic,space group C2/c with a=34.448（11） ,b=5.563 2（17）,c=18.509（6）,β=118.830（8）°,V=3 107.4（17）3,Z=4,Dc=1.525 g·cm-3,μ=0.753 mm-1,F（000）=1 480,R1=0.040 8,wR2=0.111 2.Ni（Ⅱ） is six-coordinated with slightly distorted octahedral coordination geometry by two N atoms from two bimb,two O atoms from two SDBA2-and two O atoms from two coordinated water molecules.The Ni（Ⅱ） is bridged by the SDBA2-into a wavy chain,which is further linked into grid network by bimb.
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