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富Cu团簇的析出对RPV模拟钢韧-脆转变温度的影响
  • ISSN号:0412-1961
  • 期刊名称:金属学报
  • 时间:2012.6.6
  • 页码:753-758
  • 分类:TL341[核科学技术—核技术及应用]
  • 作者机构:[1]上海大学材料研究所,上海200072, [2]上海大学微结构重点实验室,上海200444, [3]中国核动力研究设计院核燃料及材料国家重点实验室,成都610041
  • 相关基金:国家重点基础研究发展计划项目2011CB610503; 国家自然科学基金项目50931003; 上海市重点学科建设项目S30107资助
  • 相关项目:金属材料合金相的早期析出行为的实验与理论研究
中文摘要:

将Cu含量高于实际核反应堆压力容器(RPV)钢的模拟钢在880℃水淬后,在660℃进行调质处理,然后在370℃时效不同时间,采用TEM,原子探针层析法(APT)和冲击实验对其进行研究.结果表明,时效1150 h后,富Cu团簇的析出仍处于形核阶段,对韧-脆转变温度(DBTT)没有明显的影响;时效3000 h后,试样中析出了平均尺寸为1.5 nm的富Cu团簇,主要分布在位错线上,数量密度达到4.2×10~(22)m~(-3),DBTT由调质处理后的-100℃升高至-60℃;时效13200 h后,富Cu团簇略有长大,平均尺寸达到2.4 nm,团簇的数量密度与时效3000 h的试样处于相同数量级,DBTT升高至-45℃.采用热时效方法使富Cu团簇析出后,DBTT只提高了55℃,没有中子辐照引起的那样显著,这不仅是因为富Cu团簇的数量密度低,基体中没有中子辐照产生的晶体缺陷也是重要的原因.

英文摘要:

Reactor pressure vessels(RPVs) are usually made of low alloy ferritic steels,among which A508-Ⅲsteel is a typical one.The long-term neutron irradiation can induce the embrittlement of RPV steels,and the embrittlement may lead to a reduction of the RPV service life.Generally, this behavior of the embrittlement is well established and is typically assessed by the increase in the ductile-to-brittle transition temperature(DBTT) of the RPV steels.For many years,extensive studies have revealed that irradiation-induced ultrafine Cu-rich clusters(CRCs) play an important role and CRCs with high number density cause hardening and embrittlement of the RPV steels.In order to investigate the effect of the precipitation of CRCs on DBTT of RPV steels by thermal aging,it is necessary to increase the Cu content in RPV steel.A 40 kg ingot of RPV simulated steel based on the composition of A508-Ⅲsteel with higher Cu content(0.6%in mass fraction) was prepared by vacuum induction melting,and it was forged and hot rolled to a plate with 7 mm in thickness.Specimens with a dimension of 7 mm×12 mm×60 mm were cut from the hot-rolled plate.The heat treatment routes of the specimens consists of a soaking at 880℃for 0.5 h,a water quenching,a tempering at 660℃for 10 h,and a final aging at 370℃for various times.The effect of the precipitation of CRCs on the DBTT of the RPV simulated steel was investigated by Charpy impact tests,as well as the microstructure analysis was carried out by TEM and atom probe tomography(APT).According to ASME 23 standard,Charpy-V specimens with a dimension of 5 mm×10 mm×55 mm were prepared and tested by TINIUS OLSEN 84 impact test machine.The TEM analysis shows that CRCs precipitate on dislocations in the specimen aged at 370℃for 3000 h,and the clusters become a little coarsened when the aging time is extended to 13200 h.For the specimens aged for 1150 h,CRCs were on the stage of the nucleation assessed by TEM as well as APT analysis,and they did not have an effect on the DBTT of

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期刊信息
  • 《金属学报》
  • 中国科技核心期刊
  • 主管单位:中国科学协术协会
  • 主办单位:中国金属学会
  • 主编:柯俊
  • 地址:沈阳文化路72号
  • 邮编:110016
  • 邮箱:shxiao@imr.ac.cn
  • 电话:024-23971286
  • 国际标准刊号:ISSN:0412-1961
  • 国内统一刊号:ISSN:21-1139/TG
  • 邮发代号:2-361
  • 获奖情况:
  • 第一、二届全国优秀科技期刊评比一等奖,第一、二、三届国家期刊奖,国家期刊方阵"双高"期刊,第一、二、三届中国科学院科技期刊评比一等奖,中国科学院优秀期刊特别奖,第一、二、三、五届中国科协优秀科技期刊评比一等奖,中国科协精品期刊工程A类、B类,第一、二、三、四、五届中国百种杰出学术期刊,首届出版政府奖
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  • 被引量:26785