采用批实验法对沈阳张士灌区2种不同重金属污染负荷的土壤(A清洁土壤;B高污染土壤)中不同浓度组合的Cd^2+和Pb^2+的吸附.解吸动力学行为进行比较研究.结果表明,清洁土壤A对Cd^2+和Pb^2+的吸附能力高于高污染负荷土壤B.Elovich方程是描述这2种土壤Cd^2+和Pb^2+吸附动力学行为的最优模型,其次为双常数方程,最差模型是一级动力学方程.2种土壤Cd^2+、Pb^2+的解吸速率随重金属初始浓度增加而增加,随解吸时间的延长而不断降低.描述这2种土壤Cd^2+、Pb^2+解吸动力学过程的最优模型为Elovich方程,其次为双常数方程,而一级动力学方程拟合效果不佳.
Sorption-desorption dynamic behavior by the batch method on two different metal Zhangshi irrigation area in Shenyang. The of Cd, Pb with different concentrations was studied burden soils ( A : clean soil; B : high polluted soil) of results indicated that the sorption capacity of clean soil to Cd^2+ and Pb^2+ was larger than that of higher metal burden soil. Elovich equation was the best model to describe the sorption kinetics of Cd^2+ and Pb^2+ , and then was two-constant equation,the worst model was first-order dynamics equation. The desorptive rates of Cd^2+ and Pb^2+ in two soils were increased with the higher initial concentrations of Cd^2+ and Pb^2+ in the treatments, and decreased with the increasing desorpive time. Elovich equation was the optimal model to describe the desorption kinetics of Cd^2+ and Pb^2+ in the two soils, and then was twoconstant equation, while the relative effect of first-order dynamics equation was not good.