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中文摘要：
合成了一种新型的室温天蓝色磷光发射材料双（2-二苯基磷苯基）醚碘合铜（Ⅰ）（[（POP）CuI]2）配合物。通过红外光谱、X-射线单晶衍射确定其分子结构,并对其光电特性进行了详细研究。结果表明：[（POP）CuI]2为二聚体结构,主要吸收峰为227,268,291 nm,最大发射峰为475 nm,光学带隙为2.93 eV。以[（POP）CuI]2作为客体掺杂在主体CBP中作为发光层,制备了结构为ITO/NPB（30 nm）/CBP∶[（POP）CuI]2（30 nm,8%）/BAlq（10 nm）/Alq3（30 nm）/LiF（1 nm）/Al（200 nm）的器件,其电致发光峰为476 nm,最大亮度为9 539 cd/m2,最大电流效率为1.9 cd/A。
英文摘要：
A new copper（Ⅰ） complex of [（POP）CuⅠ]2 ∶bis-[2-（diphenyl phosphino）phenyl]ether] with blue emission was designed and synthesized.The molecular structure and photophysical properties of [（POP）CuⅠ]2 were investigated by FT-IR spectra,X-ray single crystal diffraction,UV-Vis absorption,emission spectra and cyclic voltammetry.The results indicate that the UV-Vis absorption peaks of [（POP）CuⅠ]2 are located at 227,268 and 291 nm.The blue light can be observed with a peak at 475 nm in the solid state.The HOMO,LUMO energy levels and optical gap are-6.40,-3.47 and 2.93 eV,respectively.The devices of ITO/NPB（30 nm）/CBP∶[（POP）CuⅠ]2（30 nm,8%）/BAlq（10 nm）/Alq3（30 nm）/LiF（1 nm） /Al（200 nm） were fabricated by doping [（POP）CuⅠ]2 into CBP as emitting layer with emission peak at 476 nm and maximum luminance,current efficiency of 9 539 cd/m2,1.9 cd/A.
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