将不同浓度的二[2-(4,三氟甲基-2-羟基苯基)](Zn(4-TfmBTZ)2)掺杂到mcp层中制备了有机电致发光器件(OLED),器件的结构为IT0/NPB(40nm)/EZn(4-TfmBTZ)28%:mcp](30nm)/Bphen(40nm)/LiF(1nm)/Al(200nm)。结果发现,Zn(4-TfmBTZ)2的掺杂浓度极大地影响器件的光谱和色度。在mcp层中,Zn(4-TfmBTZ)2质量分数为8%时,Zn(4-TfmBTz)2与电子传输层Bphen形成的激基复合物发射较强;但在掺杂浓度达到50%时,激基复合物的发射非常弱,几乎消失。由此通过mcp中Zn(4-TfmBTZ)2掺杂浓度的调节,实现了器件从蓝光色坐标为(0.22,0.27)到白光色坐标为(0.29,0.34)发射的调控。
The doping devices with structure of ITO/NPB/mcp. Zn(4-TfmBTZ)z/Bphen/LiF/Al are fabricated,where the Zn(4-TfmBTZ)2 mass fraction in mcp layer is 8% and 50% ,respectively. The results show that the mass fraction of Zn(4-TfmBTZ)2 in mcp layer has important effect on the device performance,which contains spectrum and chromaticity. When the Zn(4-TfmBTZ)2 mass fraction is 8%, there exists a strong exeiplex emission of Zn(4-TfmBTZ) 2 and Bphen, while when the Zn(4-TfmB- TZ) 2 mass fraction is enhanced to 50 %, the exciplex emission almost disappears. The light color is tuned from blue light CIEx,y(0.22,0. 27)to white light CIEx,y (0.29,0. 34) at the same voltage by changing the Zn(4-TfmBTZ)2 doping amount in mop layer.