合成了2,7,12-三烯丙基-3,8,13三甲氧基10,15-二氢-三苯环壬烷(CTV烯丙基衍生物),该衍生物与C60,作用的紫外光谱表明:CTV烯丙基衍生物不仅能通过立体互补性和电子互补性形成包结化合物,并且末端烯丙基上的双键有助于形成更稳定的包结化合物.
2,7, 12-triallyl-3,8, 13-trimethoxy-10, 15-dihydro-5H-tribenzo-[a d g] cyclononene was synthesized and the interaction with C60 were studied by UV spectra. The results show that the host-guest complexe was formed though size match and electron donor-accept interaction. In addition,the association constant was typically big comparing with other CTV derivatives because the conjugated π-systems were formed between p-electron of allyl and a-electrons system of C60.