用柠檬酸络合法制备了钙钛矿型GdCo1-xSrxO3(X=0.00,0.02,0.04,0.06,0.08)复合氧化物,通过XRD,TEM等手段对所生成纳米晶的物相结构、微观形貌、颗粒大小等进行了表征.结果表明,所合成的颗粒为钙钛矿型纳米晶,球形.通过其对活性艳红X-3B降解对其光催化活性进行了研究,实验结果表明在B位掺杂Sr^2+后使GdC003的光催化活性明显提高,当X=0.06时,即GdCo1-xSrxO3的光催化活性最佳.
A series of perovskite type compounds GdCo1-xSrxO3 (x =0.00 , 0.02, 0.04, 0.06, 0.08 ) were prepared by citrate complexing method. The structure, size and appearance of the synthesized nanoparticles were characterized by XRD, TEM. The results show that the as-prepared GdCol.x Srx 03 nanoparticles are perovskite structure and spherical appearance. The photocatalytic activity of GdCo1-xSrxO3 nanoparticles meatured the deg- radation of Reactive Brilliant Red X-3B , the results show that B-site doping can notly improve the photocatalytic activity of GdCoO3 and GdCo.94Sr0.06O3was the best one .