位置：成果数据库 > 期刊 > 期刊详情页
基于四核钴夹心结构单元构建的一维杂化多金属氧酸盐
  • 期刊名称：科学通报, 12期, pp 902-907, 2011/4/25(中国知网).
  • 时间：0
  • 分类：O614.122[理学—无机化学;理学—化学]
  • 作者机构：[1]中国科学院福建物质结构研究所,结构化学国家重点实验室,福州350002
  • 相关基金：国家杰出青年科学基金（20725101）、国家重点基础研究发展计划（2011CB932504）、国家自然科学基金（50872133,20821061）和福建省自然科学基金（2008F3120）资助项目
  • 相关项目：新颖手性及非心结构金属硼酸盐的设计合成及性能
关键词： 水热合成, 钴, 多金属氧酸盐, 夹心, hydrothermal synthesis, cobalt, polyoxometalates, sandwich
中文摘要：

通过水热法合成了一个新颖的有机．无机杂化四核钴夹心一维多金属氧酸盐：Na（H2O）2[co（en）3】3H3【Co4（H2O）2（B—α-PW9034）2]·10．5H2O（1）（en=ethylenediamine），并利用X射线单晶衍射技术确定其结构．实验结果表明，该化合物是由四核钴夹心的多阴离子单G[Co4（H2O）2（B-α-PW9034）2】10-通过Na＋子桥连形成的一维链状结构，同时对化合物进行了红外、热重、元素分析和粉末衍射等表征．

英文摘要：

A one-dimensional polyoxotungstate, Na（H2O）2[Co（en）3]3H3[Co4（H2O）2（B-α-PW9O34）2]· 10.5H2O （en=ethylenediamine）, was hydrothermally synthesized and characterized by single crystal X-ray diffraction, infrared spectroscopy, thermogravimetric analysis, and powder X-ray diffraction, respectively. The structure was constructed from the [Co4（H2O）2（B-α-PW9034）2]- units, in which a tetra-cobalt cluster core was sandwiched between two PW90349- polyanions, that were further connected via Na＋ cations forming a one-dimensional chain structure.

同期刊论文项目
新颖手性及非心结构金属硼酸盐的设计合成及性能
期刊论文 42 会议论文 39 著作 2
功能材料的结构化学
期刊论文 171 获奖 4
无机合成和制备化学
期刊论文 81 会议论文 71 著作 1
同项目期刊论文
Hydrothermal Synthesis and Crystal Structure of a Novel Sandwich Germanotungstate: [Ni(dien) (H2O)3]
Two Novel 1-D Organic-Inorganic Composite Phosphotungstates Cons- tructed from [Ln(α-PW11O39)2]11- U
A series of 3d-4f heterometallic frameworks comprising 2D lanthanide-organic layers and diverse Cu-c
A new 3-D Gd-Cu heterometallic poly- mer [Gd2Cu3(bpy)2(ip)6]·6H2O with a non-interpenetrated alpha-P
A Supramolecular Network Cons- tructed from {Er2} and {Cu2} Units
The first polyoxometalate-templated four-fold interpenetrated coordination polymer with new topology
Oxo Boron Clusters and Their Open Frameworks
(CH3NH3)2[GeB4O9]: An organically- templated chiral borogermanate with second-order nonlinear and fe
(en)Mn2(V2O7): A 3D manganese vanadate built by Mn-O layers and two types of pillars of V2O7 and en
Two New Dawson-Type Polyoxometa- lates: 1D Chain Made by Mono- Dawson Units and 2D Layer Made by Dou
Hydrothermal Synthesis and Structural Characterization of a New Keggin- Type Tungstogermanate Contai
Lanthanide-Organic Frameworks Based on {Ln4(μ3-OH)4(μ2-OH)2} Cluster Units
An Alcohol-templated Borate Based on [B14O20(OH)6]4- Polyborate Anions
A series of Ni6-substituted polyoxo- metalates derivated from tripodal alcohol ligands
Hydrothermal Synthesis and Crystal Structure of a New 2-D Organic- Inorganic Hybrid Wells-Dawson-Typ
Hydrothermal Synthesis and Structural Characterization of Three One-Dimen- sional Heteropolytungstat
A Series of Open-Framework Alumino- borates Templated by Transition-Metal Complexes
Lanthanide Germanate Cluster Organic Frameworks Constructed from {Ln8Ge12} or {Ln11Ge12} Cage Cluste
Hydrothermal Synthesis and Structure of A Novel Organic-Inorganic Hybrid Polyoxotungstate: H5[Cu(en)
A new layered aluminoborate [Zn- (dien)2][{Al(OH)}{B5O9F}] templated by transition metal complexes
Poly(polyoxotungstate)s with 20 Nickel Centers: From Nanoclusters to One-Dimensional Chains
A Series of Vanadogermanates from 1D Chain to 3D Framework Built by Ge-V- O Clusters and Transition-
The first three-fold interpenetrated framework with two different four- connected uniform nets of 66
Combination Chemistry of Hexa- Copper-Substituted Polyoxometalates Driven by the CuII-Polyhedra Dist
Two additive-induced isomeric alumino -borates templated by methylamine
Metal-Organogermanate Frameworks Built by Two Kinds of Infinite Ge-O Chains with High Thermostabilit
High-Nuclearity Ni-Substituted Poly- oxometalates: A Series of Poly(poly- oxotungstate)s Containing
Germanate Frameworks Constructed from Oxo Germanium Cluster Building Units
A Series of 1-D Lanthanide Coordi- nation Polymers Based on [Ln4(μ3- OH)4] (Ln = Er, Tb, Gd) Cluster
Synthetic Chemistry of Cluster Compounds
A Series of Lanthanide Coordination Polymers Constructed from 4-Pyridin-4-ylbenzoate
具有非穿插α-Po拓扑的Gd-Cu异金属配聚物 [Gd2Cu3 （bpy）2（ip）6]·6H2O
新颖四核镍夹心的杂化锗钨酸盐的合成、结构与表征（英文）
A new 3-D Gd-Cu heterometallic polymer [Gd2Cu3（bpy）2- （ip）6]·6H2O with a non-interpenetrated α-Po net
Designed synthesis of POM-organic frameworks from {Ni(6)PW(9)} building blocks under hydrothermal co
Linking two distinct layered networks of nanosized {Ln(18)} and {Cu-24} wheels through isonicotinate
The first di-cadmium-substituted vanadoarsenate derived from alpha-{As(8)V(14)O(42)} shell
Hydrothermal synthesis and structure of di-copper(II)-complex substituted monovacant polyoxotungstat
0-D and 1-D inorganic-organic composite polyoxotungstates constructed from in-situ generated monocop
Incorporating distinct metal clusters to construct diversity of 3D pillared-layer lanthanide-transit
Hydrothermal synthesis and structural characterization of two 1-D and 2-D Dawson-based phosphotungst
3D lanthanide-transition-metal-organic frameworks constructed by two distinct tetranuclear units of
Hydrothermal synthesis and crystal structure of a new hexa-cobalt-containing POM
GeB4O9 center dot H(2)en: An organically templated borogermanate with large 12-ring channels built b
Three inorganic-organic composite polyoxotungstates: Syntheses, characterization and structures of [
The first solid composed of {As(4)V(16)O(42)(H(2)O)} clusters
Hydrothermal Synthesis and Structural Characterization of Two Organic-Inorganic Hybrids Based on San
Two hexanickel-substituted Keggin-type germanotungstates
An unusual eight-connected self-penetrating ilc net constructed by dinuclear lanthanide building uni
The effect of mixed amines on the competitive formation of two open-framework zinc phosphates with 1
Cubic Polyoxometalate-Organic Molecular Cage
Lanthanide-Organic Frameworks Based on {Ln(4)(mu(3)-OH)(4)(mu(2)-OH)(2)} Cluster Units
Hydrothermal Synthesis and Structure of A Novel Organic - Inorganic Hybrid Polyoxotungstate: H(5)[Cu
Hydrothermal Synthesis and Structural Characterization of Three One-Dimensional Heteropolytungstates
(en)Mn-2(V2O7): A 3D manganese vanadate built by Mn-O layers and two types of pillars of V2O7 and en
Hydrothermal Synthesis and Crystal Structure of a New 2-D Organic-Inorganic Hybrid Wells-Dawson-Type
Two Novel 2D Lanthanide-organic Frameworks Based on Different Carboxylate-containing Mixed Ligands
Hydrothermal Synthesis and Structure of One New Polyoxotungsate [Ni(trien)](4)[Ni(4)(H(2)O)(2)(HPW(9
(CH(3)NH(3))(2)[Ge(B(4)O(9))]: An organically-templated chiral borogermanate with second-order nonli
A Series of Vanadogermanates from 1D Chain to 3D Framework Built by Ge-V-O Clusters and Transition-M
A Supramolecular Network Constructed from {Er(2)} and {Cu(2)} Units
The first three-fold interpenetrated framework with two different four-connected uniform nets of 6(6
A New Organic-Inorganic Hybrid Layered Molybdenum(V) Cobalt Phosphate Constructed from [H(24)(Mo(16)
A series of Ni(6)-substituted polyoxometalates derivated from tripodal alcohol ligands
Hydrothermal Synthesis and Crystal Structure of a Novel Sandwich Germanotungstate: [Ni(dien)(H(2)O)(
A new conformer of indium germanate InGe(3)O(7.5)(en): conformational polymorphism in germanate fami
Two New Dawson-Type Polyoxometalates: 1D Chain Made by Mono-Dawson Units and 2D Layer Made by Double
A new layered aluminoborate [Zn(dien)(2)][{Al(OH)}{B(5)O(9)F}] templated by transition metal complex
Aluminoborates with Open Frameworks: Syntheses, Structures, and Properties
A banana-shaped iron(III)-substituted tungstogermanate containing two types of lacunary polyoxometal
Synthesis and Description of a Novel Metal-organic Framework Based on Trigonal Prismatic Building Bl
Zero- and One-dimensional Organic-inorganic Hybrid Compounds Based on Monovacant Keggin Polyoxotungs
Hydrothermal Synthesis, Structure and Magnetic Property of a Novel Hexa-Ni(II) Substituted Polyoxome
An Alcohol-templated Borate Based on [B(14)O(20)(OH)(6)](4-) Polyborate Anions
Hydrothermal Synthesis and Structure of One New Vanadoarsenate [Zn(dien)(Hdien)](2)[As(6)V(15)O(42)(
A 3-D Supramolecular Framework with Open Channels Constructed from Lanthanide Ions and Mixed Ligands
Hydrothermal Synthesis and Structural Characterization of two Hybrid Keggin-based Polyoxometalates
A new 3-D Gd-Cu heterometallic polymer [Gd2Cu3(bpy)(2)(ip)(6)]center dot 6H(2)O with a non-interpene
A Series of 1-D Lanthanide Coordination Polymers Based on [Ln(4)(mu(3)-OH)(4)] (Ln = Er, Tb, Gd) Clu
Lanthanide Germanate Cluster Organic Frameworks Constructed from {Ln(8)Ge(12)} or {Ln(11)Ge(12)} Cag
Novel Hybrids Constructed from Keggin-Polyoxometalate and Mixed Copper Complex
Combination Chemistry of Hexa-Copper-Substituted Polyoxometalates Driven by the Cu-II-Polyhedra Dist
A New 2D Hybrid Indate-Germanate Based on the Linkages of Ge(4)O(10)F(2) Clusters and {In(2)O(6)} Di
Two Novel 1-D Organic-Inorganic Composite Phosphotungstates Constructed from [Ln(alpha-PW11O39)(2)](
A New 2-D Network Containing {As4V16O42(H2O)} Cluster Units
Two 3-D Supramolecular Networks Containing Dimeric {Cu2X2} Cluster Units
High-Nuclearity Ni-Substituted Polyoxometalates: A Series of Poly(polyoxotungstate)s Containing 20-2
Open-framework aluminoborates co-templated by two types of primary amines
Hydrothermal Synthesis and Structural Characterization of a New Keggin-Type Tungstogermanate Contain
Two-dimensional extended (4,4)-topological network constructed from Tetra-Ni-II-Substituted sandwich
In situ ligand reactions under hydrothermal conditions afford a novel zinc-substituted polyoxovanada
{Ln(III)[mu(5)-K-2,K-1,K-1,K-1,K-1-1,2-(CO2)(2)C6H4][isonicotine][H2O]}( 2)Cu-I center dot X (Ln = e
Extended Architectures constructed from sandwich tetra-metal-substituted polyoxotungstates and trans
Combination of lacunary polyoxometalates and high-nuclear transition-metal clusters under hydrotherm
Hydrothermal synthesis and structural characterization of three inorganic-organic composite sandwich
A series of lanthanide-transition metal frameworks based on 1-, 2-, and 3D metal-organic motifs link
A combination of lacunary polyoxometalates and high-nuclear transition-metal clusters under hydrothe
具有非穿插α-Po拓扑的Gd-Cu异金属配聚物 [Gd2Cu3 （bpy）2（ip）6]·6H2O
新颖四核镍夹心的杂化锗钨酸盐的合成、结构与表征（英文）
A new 3-D Gd-Cu heterometallic polymer [Gd2Cu3（bpy）2- （ip）6]·6H2O with a non-interpenetrated α-Po net
Zero- and One-dimensional Organic-inorganic Hybrid Compounds Based on Monovacant Keggin Polyoxotungstates
Topological variability of Zn(II) and Co(II) 3D coordination polymers obtained through solvothermal
Solvent and temperature influence structural variation from nonporous 2D -> 3D parallel polycatenati
A non-interpenetrated porous metal-organic framework with high gas-uptake capacity
A Series of New Infrared NLO Semiconductors, ZnY(6)Si(2)S(14), Al(x)Dy(3)(Si(y)Al(1-y))S(7), and Al(
BaNbO(IO(3))(5): A New Polar Material with a Very Large SHG Response
Pd(O2CCF3)(2)/Benzoquinone: A Versatile Catalyst System for the Decarboxylative Olefination of Arene
A Series of Novel Lanthanide(III) Trisulfonates Based on Dinuclear Clusters
NaVO(2)(IO(3))(2)(H(2)O): A Unique Layered Material Produces A Very Strong SHG Response
Synthesis, Crystal Structures, and Luminescent Properties of Two Series'; of New Lanthanide (III) Am
Explorations of new quaternary phases in the Ln(III)-V(V)(d(0))-Se(IV)-O (Ln = Nd, Eu, Gd, Tb) syste
Syntheses and crystal structures of four new silver(I) iodates with d(0)-transition metal cations
A Series of New Ternary and Quaternary Compounds in the Li(I)-Ga(III)-Te(IV)-O System
Syntheses and Crystal Structures of a Series of Alkaline Earth Vanadium Selenites and Tellurites
A Series of New Phases Containing Three Different Asymmetric Building Units
A New Molybdenum-Oxide-Based Organic-Inorganic Hybrid Compound Templated by 5-(2-Pyridyl)tetrazole w
Assembly of a metal-organic framework by sextuple intercatenation of discrete adamantane-like cages
A Series of Polynuclear Complexes of d(10) Metals With Interesting Luminescent Properties
A new IR non-linear optical material with 2D 3-fold interpenetrated topology
Stabilization of (SnS(4))(4-) anion by coordinating to [TM(pi-conjugated-ligand)(m)](n+) complex: a
Conformational Isomerism of 1,2-Bis(imidazol-1 ';-yl)ethane Affected by the Orientation of Functiona
Pd(OAc)(2)-Catalyzed Oxidative C-H/C-H Cross-Coupling of Electron-Deficient Polyfluoroarenes with Si
A DFT study on the Pd-mediated decarboxylation process of aryl carboxylic acids
A Series of Open-Framework Aluminoborates Templated by Transition-Metal Complexes
Polar or Non-Polar? Syntheses, Crystal Structures, and Optical Properties of Three New Palladium(II)
Explorations of New Second-Order Nonlinear Optical Materials in the K(I)-M(II) -I(V)-O Systems
Hydrothermal syntheses, crystal structures and magnetic properties of two new mixed metal copper(I)
Syntheses, crystal structures, and properties of three new lanthanum(III) vanadium iodates
A New Transparent Conductor: Silver Nanowire Film Buried at the Surface of a Transparent Polymer
Spontaneous asymmetrical crystallization of a three-dimensional diamondoid framework material from a
Two additive-induced isomeric aluminoborates templated by methylamine
Structural overview and structure-property relationships of iodoplumbate and iodobismuthate
Magnetic lanthanide-transition-metal organic-inorganic hybrid materials: From discrete clusters to e
New Types of 3D Organically Templated Zn(2+)/Cd(2+)-Cu(+) Mixed Metal Sulfites
Palladium-Catalyzed Direct Arylation of Electron-Deficient Polyfluoroarenes with Arylboronic Acids
Thermally stable helical chain and octanuclear Ag(I) coordination networks with yellow luminescence
Conversion from ILCT to LLCT/MLCT Excited State by Heavy Metal Ion Binding in Iridium(III) Complexes
Low-valence oxo-centred triruthenium complexes by bridging acetate substitution with pyrazolyldiazin
Spontaneous chiral resolution, nonlinear optical and luminescence of eight-coordinate lanthanide(III
Explorations of New Phases in the Ga(III)/In(III)-Cu(II)-Se(IV)-O System
Explorations of new phases in the Ga(III)/In(III)-Mo(VI)-Se(IV)/Te(IV)-O systems
Explorations of new second-order NLO materials in the Ag(I)-Mo(VI)/W(VI)-Te(IV)-O systems
New Types of Luminescent Lanthanide Squarato-Aminophosphonates
A facile approach to hexanary chalcogenoborate featuring a 3-D chiral honeycomb-like open-framework
A luminescent homochiral 3D Cd(II) framework with a threefold interpenetrating uniform net 8(6)
An interwoven Fe3L3 trigonal metallamacrocycle from an in situ ligand hydrolysis reaction
1D Infinite silver(I) chains reside in the big cavities built by the novel p-sulfonatocalix[4]arene-
High-Temperature Formation of Titanate Nanotubes and the Transformation Mechanism of Nanotubes into
Hydrogen-Bonded Helical Array, Sodium-Ion-Mediated Head-to-Tail Chain, and Regular Ionic Bilayer: St
Ln(3)Pb(3)(IO(3))(13)(mu(3)-O) (Ln = La-Nd): New Types of Second-Order Nonlinear Optical Materials C
Luminescence vapochromic properties of a platinum(II) complex with 5,5 ';-bis(trimethylsilylethynyl)
Luminescence Vapochromism of a Platinum(II) Complex for Detection of Low Molecular Weight Halohydroc
Hydrothermal Syntheses, Crystal Structures, And Magnetic Properties of a Series of Complexes Constru
Ca(10)Ge(16)B(6)O(51) and Cd(12)Ge(17)B(8)O(58): Two Types of New 3D Frameworks Based on BO(4) Tetra
Ba(3)[Ge(2)B(7)O(16)(OH)(2)](OH)(H(2)O) and Ba(3)Ge(2)B(6)O(16): Novel Alkaline-Earth Borogermanates
A ligand-conformation driving chiral generation and symmetry-breaking crystallization of a zinc(II)
A Versatile Tripodal Host with Cylindrical Conformation: Solvatomorphism, Inclusion Behavior, and Se
From discrete octahedral nanocages to 1D coordination polymer: Coordination-driven a single-crystal-
Mechanism of silver- and copper-catalyzed decarboxylation reactions of aryl carboxylic acids
An iridium(III) complex of oximated 2,2 ';-bipyridine as a sensitive phosphorescent sensor for hypoc
具有非穿插α-Po拓扑的Gd-Cu异金属配聚物 [Gd2Cu3 （bpy）2（ip）6]·6H2O
A new 3-D Gd-Cu heterometallic polymer [Gd2Cu3（bpy）2- （ip）6]·6H2O with a non-interpenetrated α-Po net
Zero- and One-dimensional Organic-inorganic Hybrid Compounds Based on Monovacant Keggin Polyoxotungstates