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中文摘要：
本项目聚焦无机合成和制备化学，在水热及溶剂热条件下开展金属-氧簇及非金属-氧簇的合成及性能研究，主要开展了以下几方面工作研究了金属-氧簇及非金属-氧簇的形成及聚合条件，同时对簇合物的结构、谱学及热稳定性等进行了研究；研究了不同结构类型金属-氧簇的组合条件并取得重要进展；研究了不同属性簇单元间的组合条件、簇合物的结构及谱学等；考察了金属离子、有机配体、前驱体、结构导向剂、结构稳定剂、反应时间、反应温度、溶液的酸碱性及反应配比等因素对金属-氧簇单晶体形成的影响，获得的合成经验和规律对今后定向合成具有不同功能的簇合物奠定了基础，同时考察了合成条件与结构间的关系，总结了合成条件与不同结构及不同属性簇合物间的组装及组合规律；研究了相关簇合物的磁性、电学、发光及二阶非线性光学性能等。本项目的研究不仅发现了新的学科生长点，而且推动了合成化学、原子簇化学、结构化学及材料化学的发展，具有重要的科学意义。
结论摘要：
英文主题词synthetic and preparative chemistry; cluster chemistry; structures; characterization; properties
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期刊论文
Designed synthesis of POM-organic frameworks from {Ni(6)PW(9)} building blocks under hydrothermal co
Linking two distinct layered networks of nanosized {Ln(18)} and {Cu-24} wheels through isonicotinate
Hydrothermal synthesis and structure of di-copper(II)-complex substituted monovacant polyoxotungstat
0-D and 1-D inorganic-organic composite polyoxotungstates constructed from in-situ generated monocop
Incorporating distinct metal clusters to construct diversity of 3D pillared-layer lanthanide-transit
Hydrothermal synthesis and structural characterization of two 1-D and 2-D Dawson-based phosphotungst
GeB4O9 center dot H(2)en: An organically templated borogermanate with large 12-ring channels built b
Three inorganic-organic composite polyoxotungstates: Syntheses, characterization and structures of [
Hydrothermal Synthesis and Structural Characterization of Two Organic-Inorganic Hybrids Based on San
An unusual eight-connected self-penetrating ilc net constructed by dinuclear lanthanide building uni
The effect of mixed amines on the competitive formation of two open-framework zinc phosphates with 1
Hydrothermal Synthesis and Structure of A Novel Organic - Inorganic Hybrid Polyoxotungstate: H(5)[Cu
Hydrothermal Synthesis and Structural Characterization of Three One-Dimensional Heteropolytungstates
(en)Mn-2(V2O7): A 3D manganese vanadate built by Mn-O layers and two types of pillars of V2O7 and en
Hydrothermal Synthesis and Crystal Structure of a New 2-D Organic-Inorganic Hybrid Wells-Dawson-Type
Hydrothermal Synthesis and Structure of One New Polyoxotungsate [Ni(trien)](4)[Ni(4)(H(2)O)(2)(HPW(9
(CH(3)NH(3))(2)[Ge(B(4)O(9))]: An organically-templated chiral borogermanate with second-order nonli
A Series of Vanadogermanates from 1D Chain to 3D Framework Built by Ge-V-O Clusters and Transition-M
The first three-fold interpenetrated framework with two different four-connected uniform nets of 6(6
A New Organic-Inorganic Hybrid Layered Molybdenum(V) Cobalt Phosphate Constructed from [H(24)(Mo(16)
Hydrothermal Synthesis and Crystal Structure of a Novel Sandwich Germanotungstate: [Ni(dien)(H(2)O)(
A new conformer of indium germanate InGe(3)O(7.5)(en): conformational polymorphism in germanate fami
Two New Dawson-Type Polyoxometalates: 1D Chain Made by Mono-Dawson Units and 2D Layer Made by Double
A new layered aluminoborate [Zn(dien)(2)][{Al(OH)}{B(5)O(9)F}] templated by transition metal complex
A banana-shaped iron(III)-substituted tungstogermanate containing two types of lacunary polyoxometal
Synthesis and Description of a Novel Metal-organic Framework Based on Trigonal Prismatic Building Bl
Zero- and One-dimensional Organic-inorganic Hybrid Compounds Based on Monovacant Keggin Polyoxotungs
Hydrothermal Synthesis, Structure and Magnetic Property of a Novel Hexa-Ni(II) Substituted Polyoxome
Hydrothermal Synthesis and Structure of One New Vanadoarsenate [Zn(dien)(Hdien)](2)[As(6)V(15)O(42)(
A 3-D Supramolecular Framework with Open Channels Constructed from Lanthanide Ions and Mixed Ligands
A new 3-D Gd-Cu heterometallic polymer [Gd2Cu3(bpy)(2)(ip)(6)]center dot 6H(2)O with a non-interpene
A Series of 1-D Lanthanide Coordination Polymers Based on [Ln(4)(mu(3)-OH)(4)] (Ln = Er, Tb, Gd) Clu
Lanthanide Germanate Cluster Organic Frameworks Constructed from {Ln(8)Ge(12)} or {Ln(11)Ge(12)} Cag
Combination Chemistry of Hexa-Copper-Substituted Polyoxometalates Driven by the Cu-II-Polyhedra Dist
A New 2D Hybrid Indate-Germanate Based on the Linkages of Ge(4)O(10)F(2) Clusters and {In(2)O(6)} Di
Two Novel 1-D Organic-Inorganic Composite Phosphotungstates Constructed from [Ln(alpha-PW11O39)(2)](
High-Nuclearity Ni-Substituted Polyoxometalates: A Series of Poly(polyoxotungstate)s Containing 20-2
Hydrothermal Synthesis and Structural Characterization of a New Keggin-Type Tungstogermanate Contain
Two-dimensional extended (4,4)-topological network constructed from Tetra-Ni-II-Substituted sandwich
In situ ligand reactions under hydrothermal conditions afford a novel zinc-substituted polyoxovanada
{Ln(III)[mu(5)-K-2,K-1,K-1,K-1,K-1-1,2-(CO2)(2)C6H4][isonicotine][H2O]}( 2)Cu-I center dot X (Ln = e
Extended Architectures constructed from sandwich tetra-metal-substituted polyoxotungstates and trans
Combination of lacunary polyoxometalates and high-nuclear transition-metal clusters under hydrotherm
Hydrothermal synthesis and structural characterization of three inorganic-organic composite sandwich
A series of lanthanide-transition metal frameworks based on 1-, 2-, and 3D metal-organic motifs link
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