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A new 3-D Gd-Cu heterometallic polymer [Gd2Cu3（bpy）2- （ip）6]·6H2O with a non-interpenetrated α-Po net
  • ISSN号：0251-0790
  • 期刊名称：《高等学校化学学报》
  • 时间：0
  • 分类：O614.33[理学—无机化学;理学—化学] TE357.46[石油与天然气工程—油气田开发工程]
  • 作者机构：[1]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Fuzhou 350002, China, [2]College of Chemistry and Chemical Engineering, Henan University, Kaifeng 475000, China, [3]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou 350002, China
  • 相关基金：Supported by the National Natural Science Foundation for Distinguished Young Scholars of China （Grant No. 20725101）, Major State Basic Research Development Program of China （Grant No. 2006CB932904）, Natural Science Foundation of Fujian Province （Grant Nos. E0510030, 2008F3120）, National Natural Science Fund of China （Grant Nos. 50872133, 20821061 ）, and Knowledge Innovation Program of the CAS （Grant No. KJCX2.YW.H01）
作者： JIA XiangLi[1], ZHOU Jian[1], ZHAO JunWei[2], LI ZhaoHui[3], ZHENG ShouTian[1], YANG GuoYu[1]
关键词： 联吡啶, 聚合物, IP, 铜, 钆, 水热合成, 间苯二甲酸, 知识产权, hydrothermal synthesis, α-Po network, heterometallic polymer
中文摘要：

新 3-D 多孔的 Gd-Cu 异种金属性的聚合物[Gd 2 Cu 3(bpy)2(ip)6] · 6H2 O (1 )(bpy = 2,2 ′-bipyridine， H 2 ip = isophthalic 酸) 热水地被综合了，在结构上描绘了。化合物 1 在三斜晶系的空格组 P 结晶并且显示有 1-D 隧道的非贯穿的 α-Po 网络横着充满了由的 3-D hexa 原子像链(H 2 O )6 。EPR 和 1 的热稳定性被调查。

英文摘要：

A new 3-D porous Gd-Cu heterometallic polymer [Gd2Cu3（bpy）2- （ip）6]·6H2O （1） （bpy = 2,2′-bipyridine, H2ip = isophthalic acid） has been hydrothermally synthesized and structurally characterized. Compound 1 crystallizes in the triclinic space group P1and displays a 3-D non-interpenetrated α-Po net- work with 1-D channels filled transversely by the hexa-nuclear chain-like （H2O）6. The EPR and thermal stability of 1 were investigated.

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期刊信息
  • 《高等学校化学学报》
  • 北大核心期刊（2011版）
  • 主管单位:中华人民共和国教育部
  • 主办单位:吉林大学 南开大学
  • 主编：周其凤
  • 地址：吉林大学南胡校区
  • 邮编：130012
  • 邮箱：cjcu@jlu.edu.cn
  • 电话：0431-88499216
  • 国际标准刊号：ISSN：0251-0790
  • 国内统一刊号：ISSN：22-1131/O6
  • 邮发代号:12-40
  • 获奖情况:
  • 首届及第二届国家期刊奖,连续两届“百种中国杰出学术期刊”,中国期刊方阵“双高”期刊
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  • 被引量:50676