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钛铁基储氢合金在车载储能领域的应用研究
  • ISSN号:0258-7076
  • 期刊名称:《稀有金属》
  • 时间:0
  • 分类:TG146.4[金属学及工艺—金属材料;一般工业技术—材料科学与工程;金属学及工艺—金属学]
  • 作者机构:[1]钢铁研究总院功能材料研究所,北京100081, [2]北京科技大学新材料技术研究院,北京100083
  • 相关基金:国家自然科学基金项目(51371094,51471054)资助.
中文摘要:

新能源汽车的迅速发展,促进了对车载储能材料的需求和研究。钛铁基储氢合金具有室温吸放氢,可逆储氢量高,工作温区广,环保无污染,原材料成本低等特点。其不仅可以通过电化学反应实现氢的贮存,还可以直接与气态氢反应形成金属氢化物,是混合动力汽车、纯电动汽车、氢燃料电池以及氢内燃机汽车车载储能系统的重要材料。本文针对现有新能源汽车类型,介绍了主要的车载储能技术,包括:电化学储能(锂离子蓄电池、镍氢蓄电池、铅酸蓄电池)、高压储罐储能、低压储罐储能等。详细介绍了上述储能技术的工作原理,并论述了其在车载储能系统中应用的优势和不足。通过对比现有的车载储能技术,系统分析了钛铁基储氢合金在新能源汽车储能系统中应用的优势和前景,提出了需要重点改善的性能,包括:活化性能,抗毒化性能和电化学容量等,并总结了国内外相关的研究进展。

英文摘要:

The rapid development of new energy vehicles promotes the demand and research for the vehicle energy storage materials. TiFe-based hydrogen storage alloys have characteristics such as hydrogen absorption and desorption ability at room temperature, high reversible hydrogen storage capacity, wide operational temperature range, environmental protection, low raw material cost and so on. They not only can storage hydrogen by electrochemical reactions, but also can react with gaseous hydrogen directly and form metal-hy- drides, which are important materials of vehicle energy storage equipment for the hybrid electric vehicles, electric vehicles, hydrogen fuel-cell powered and burning hydrogen in internal combustion engines vehicles. This paper reviewed the main vehicle energy storage technologies including electrochemical energy storage (lithium-ion battery, nickel-hydrogen battery and lead-acid battery), high-pres- sure container energy storage and low-pressure container energy storage technologies for the existing type new energy vehicles. The working principle of the above energy storage technologies were introduced in detail, and the advantages and disadvantages of them for applying in vehicle energy storage system were discussed. By comparing the existing vehicle energy storage techniques, this paper ana- lyzed the application superiority and prospect of the TiFe-base alloys in the field of vehicle energy storage systematically, brought for- ward the performances need to be improved, such as the active performance, the anti-poisoning performance and the reversible electro- chemical capacity, and summarized the domestic and international related research progress.

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期刊信息
  • 《稀有金属》
  • 中国科技核心期刊
  • 主管单位:中国科学技术协会
  • 主办单位:北京有色金属研究总院
  • 主编:屠海令
  • 地址:北京新街口外大街2号
  • 邮编:100088
  • 邮箱:xxsf@grinm.com
  • 电话:010-82241917 62014832
  • 国际标准刊号:ISSN:0258-7076
  • 国内统一刊号:ISSN:11-2111/TF
  • 邮发代号:82-167
  • 获奖情况:
  • 中文核心期刊,冶金工业类核心期刊,中国科技论文统计源期刊
  • 国内外数据库收录:
  • 俄罗斯文摘杂志,美国化学文摘(网络版),荷兰文摘与引文数据库,美国工程索引,美国剑桥科学文摘,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版),中国北大核心期刊(2000版)
  • 被引量:13688