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Gaseous hydrogen storage thermodynamics and kinetics of RE–Mg–Ni-based alloys prepared by mechanical milling

ISSN号：1003-6326
期刊名称：《中国有色金属学报：英文版》
时间：0
分类：U473.25[机械工程—车辆工程;交通运输工程—载运工具运用工程;交通运输工程—道路与铁道工程]
作者机构：Key Laboratory of Integrated Exploitation of Baiyun Obo Multi-Metal Resources, Inner Mongolia University of Science and Technology, Department of Functional Material Research, Central Iron and Steel Research Institute
相关基金：Projects(51161015,51371094,51471054)supported by the National Natural Science Foundation of China

中文摘要：

Nanocrystalline/amorphous La Mg11Ni+x Ni(x=100%, 200%, mass fraction) composite hydrogen storage alloys were synthesized by ball milling technology. The effects of Ni content and milling time on the gaseous hydrogen storage thermodynamics and dynamics of the alloys were systematically investigated. The hydrogen desorption properties were studied by Sievert’s apparatus and a differential scanning calorimeter(DSC) connected with a H2 detector. The thermodynamic parameters(ΔH and ΔS) for the hydrogen absorption and desorption of the alloys were calculated by Van’t Hoff equation. The hydrogen desorption activation energy of the alloy hydride was estimated using Arrhenius and Kissinger methods. The results indicate that a variation in the Ni content has a slight effect on the thermodynamic properties of the alloys, but it significantly improves their absorption and desorption kinetics performances. Furthermore, varying milling time clearly affects the hydrogen storage properties of the alloys. All the as-milled alloys show so fast hydrogen absorption rate that the absorbed amount in 10 min reaches to at least more than 95% of the saturated hydrogen absorption capacity. Moreover, the improvement of the gaseous hydrogen storage kinetics of the alloys is found to be ascribed to a decrease in the hydrogen desorption activation energy caused by increasing Ni content and prolong milling time.

英文摘要：

Nanocrystalline/amorphous LaMg11Ni+xNi (x=100%, 200%, mass fraction) composite hydrogen storage alloys were synthesized by ball milling technology. The effects of Ni content and milling time on the gaseous hydrogen storage thermodynamics and dynamics of the alloys were systematically investigated. The hydrogen desorption properties were studied by Sievert’s apparatus and a differential scanning calorimeter (DSC) connected with a H2detector. The thermodynamic parameters (ΔH and ΔS) for the hydrogen absorption and desorption of the alloys were calculated by Van’t Hoff equation. The hydrogen desorption activation energy of the alloy hydride was estimated using Arrhenius and Kissinger methods. The results indicate that a variation in the Ni content has a slight effect on the thermodynamic properties of the alloys, but it significantly improves their absorption and desorption kinetics performances. Furthermore, varying milling time clearly affects the hydrogen storage properties of the alloys. All the as-milled alloys show so fast hydrogen absorption rate that the absorbed amount in 10 min reaches to at least more than 95% of the saturated hydrogen absorption capacity. Moreover, the improvement of the gaseous hydrogen storage kinetics of the alloys is found to be ascribed to a decrease in the hydrogen desorption activation energy caused by increasing Ni content and prolong milling time. ? 2017, Central South University Press and Springer-Verlag Berlin Heidelberg.