采用低温燃烧法合成SrMgAl10O17:Eu^2+及SrMgAl10O17:Eu^2+, Er^3+蓝色发光材料,通过X射线衍射仪(XRD)、扫描电子显微镜(SEM)和荧光光谱仪(PL)等测试手段对所得样品进行表征. XRD及SEM测试结果表明:利用低温燃烧法合成SrMgAl10 O17材料具有较高的结晶度,且微量的稀土元素掺杂不会破坏其晶体结构;PL测试结果表明:SrMgAl10O17:Eu^2+荧光粉在300-390 nm范围内可以被有效的激发,该波长范围与近紫外LED芯片匹配,发射光谱分布在430-520 nm之间,发射峰位于460 nm,属蓝光发射材料.共掺Er^3+可显著增强SrMgAl10O17:Eu^2+的发光强度,且当Er^3+的掺杂浓度为4%时,样品的发光强度最大,较单掺Eu^2+时样品的发光强度高出54.9%,表明Er^3+对Eu^2+的发光具有良好的敏化作用,该敏化作用的机理可以利用能量传递原理进行解释.
The SrMgAl10O17:Eu^2+ and SrMgAl10O17:Eu^2+, Er^3+ blue phosphors were synthesized by the combustion synthesis method. Their crystal structures and luminescent properties were analyzed by X-ray diffraction (XRD)、scanning electron microscope (SEM) and photoluminescence spectra, respectively. The XRD and SEM results indicate that the sample is well-crystallized in the combustion procedure, and its crystal structure has not changed when doped with low concentrations of rare-earth ions. PL results show that the phosphor of SrMgAl10O17:Eu^2+can be effectively excited by near UV LED chip with a broad emission spectrum extending from 430 nm to 520 nm, and has main peaks located at 460nm. Furthermore, the sample of the luminous intensity is the largest when the Er2+, Er^3+co-doped concentration is 4%, and the emission intensity of Sr0.95MgAl10O17:0.05Eu^2+, Er^3+phosphor is significantly enhanced 54.9%higher than that of SrMgAl10O17:Eu^2+phosphor. It is indicated that Er^3+has good sensitization effect for Eu^2+in luminescence, and this can be explained by the theory of energy transfer.