中文摘要：

采用溶胶-凝胶法制备了分别以Eu（NO3）3和Eu2（CA）3（phen）2（CA：樟脑酸;phen：1,10-菲咯啉）为前驱体,掺杂量为1%（原子摩尔比）的Eu3＋/TiO2纳米粉体,通过差热-热重（TG-DTA）、X射线衍射（XRD）、扫描电镜（SEM）、红外光谱（FTIR）、紫外-可见漫反射吸收光谱（UV-Vis）和荧光光谱等分析手段,对样品的结构和谱学性能进行了对比研究。研究表明,稀土Eu3＋以有机配合物Eu2（CA）3（phen）2为前躯体掺杂时,能更有效抑制TiO2纳米粉体的颗粒度增长和晶相转变温度;且UV-Vis吸收峰有一定的红移现象。2种样品中均产生了Eu3＋578nm（5D0→7F0）,590nm（5D0→7F1）和612nm（5D0→7F2）处的特征发射光谱峰,612nm处最强发射峰为Eu3＋特征红色发射峰。当稀土Eu3＋含量相同时,以有机配合物Eu2（CA）3（phen）2为前躯体制备的纳米粉体发光强度更大。

英文摘要：

The 1% Eu3＋ doped Eu3＋/TiO2 nano-powders were prepared via sol-gel method by using Eu（NO3）3 and Eu2（CA）3（phen）2 （CA：camphoric acid;phen：1,10-phenanthroline） as precursors respectively,and the samples were characterized by thermal analyses （TG-DTA）,X-ray powder diffraction（XRD）,scanning electron microscope（SEM）,Fourier transform infrared spectroscopy （FTIR）,UV-Vis Absorption spectra and fluorescence spectra for their microstructure,morphology and spectroscopy properties.The results of TG-DTA and XRD indicate that the increasing trend of particle size and the conversion temperature of crystalline phase of the as prepared samples was restrained when using organic complexes Eu2（CA）3（phen）2 as the do pant.The particle size was decreased from 9 to 7 nm,and the name powders were still anatase TiO2 when the calcination temperature was increased up to 500 ℃.The Absorption peak at about 370 nm in UV-Vis spectra was red-shifted when doping with organic complexes Eu2（CA）3（phen）2,namely the doped TiO2 nano powders have the ability of visible light responding.The characteristic Absorption peaks of organic complex did not appear in FTIR spectrum,indicating that the Eu3＋ has little impact on the formation process of TiO2 crystal when using Eu2（CA）3（phen）2 as precursor.The result of fluorescence spectrum indicates that the characteristic transition of Eu3＋ at 578 nm （corresponding to 5D0→7F0）,590 nm（5D0→7F1） and 612 nm （5D0→7F2） appeared in both samples,in which the peak at 612 nm was the characteristic red transmutation peak.When doping Eu3＋ with the same content,the nano-powders using Eu2（CA）3（phen）2 as precursor obtain higher luminescence intensity.Therefore,by using a simple approach,the authors prepared the light-emitting rare earth inorganic nano-powders with better luminescence property and high stability,and such inorganic nano-powders might have potential applications in many fields.